Solubility of β-HMX in Acetone plus Water Mixed Solvent Systems at Temperatures from 293.15 K to 313.15 K

被引：34

作者：

Chen, Li-Zhen ^{[1
]}

Zhang, Jing ^{[1
]}

Wang, Wen-Yan ^{[1
]}

Diao, Ying ^{[1
]}

机构：

[1] N Univ China, Sch Chem Engn & Environm, Taiyuan 030051, Peoples R China

来源：

JOURNAL OF SOLUTION CHEMISTRY | 2012年 / 41卷 / 08期

关键词：

HMX; Solubility; Liquid-solid equilibrium; Laser monitoring observation technique; Correlation; MATHEMATICAL REPRESENTATION; THERMODYNAMIC PROPERTIES; MODEL; NIBS;

D O I：

10.1007/s10953-012-9872-x

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The solubility of beta-HMX in acetone + water mixed solvents was measured using a synthetic method. The laser monitoring observation technique was used to determine the disappearance of the solid phase in a solid + liquid mixture. All data were measured at atmospheric pressure and at temperatures ranging from (293.15 to 313.15) K. The effects of solvent composition and temperature on the solubility are discussed. The experimental data were correlated with an empirical equation.

引用

页码：1265 / 1270

页数：6

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