In situ processing of epoxy composites reinforced with graphene nanoplatelets

被引:109
作者
Prolongo, S. G. [1 ]
Jimenez-Suarez, A. [1 ]
Moriche, R. [1 ]
Urena, A. [1 ]
机构
[1] Univ Rey Juan Carlos, Dept Mat Sci & Engn, Madrid 28933, Spain
关键词
Nanocomposites; Polymer-matrix composites (PMCs); Thermomechanical properties; MECHANICAL-PROPERTIES; CARBON NANOTUBES; NANOCOMPOSITES; PLATELETS; OXIDE; RAMAN;
D O I
10.1016/j.compscitech.2013.06.020
中图分类号
TB33 [复合材料];
学科分类号
摘要
Several conventional techniques for nanofiller dispersion (high shear mixing, calendering, or a combination of the two) based on applying shear mechanical forces were studied in order to analyze their efficiency in manufacturing epoxy resin reinforced with graphene nanoplatelets (GNPs). Both provide composites with uniform GNP distributions although the calendering process also induces partial exfoliation of graphene. High-shear mixing could induce the reduction of flakes' lateral size due to breakage and the rolling of nanoplatelets. Several physical properties of manufactured composites were measured. The density and glass transition temperature increase for composites manufactured by the calendering method due to the steric hindrance of exfoliated graphene nanosheets. Finally, the thermal stability of resin is increased by the addition of GNPs. The degradation temperature is increased up to 20 degrees C for composites manufactured by the calendering method. (c) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:185 / 191
页数:7
相关论文
共 25 条
[1]   Mechanical reinforcement and thermal conductivity in expanded graphene nanoplatelets reinforced epoxy composites [J].
Chatterjee, S. ;
Wang, J. W. ;
Kuo, W. S. ;
Tai, N. H. ;
Salzmann, C. ;
Li, W. L. ;
Hollertz, R. ;
Nueesch, F. A. ;
Chu, B. T. T. .
CHEMICAL PHYSICS LETTERS, 2012, 531 :6-10
[2]   Preparation and photothermal characterization of nanocomposites based on high density polyethylene filled with expanded and unexpanded graphite: Particle size and shape effects [J].
Chirtoc, Mihai ;
Horny, Nicolas ;
Tavman, Ismail ;
Turgut, Alpaslan ;
Kokey, Iskender ;
Omastova, Maria .
INTERNATIONAL JOURNAL OF THERMAL SCIENCES, 2012, 62 :50-55
[3]   Few-layer graphene under high pressure: Raman and X-ray diffraction studies [J].
Clark, S. M. ;
Jeon, Ki-Joon ;
Chen, Jing-Yin ;
Yoo, Choong-Shik .
SOLID STATE COMMUNICATIONS, 2013, 154 :15-18
[4]   The Fabrication, Properties, and Uses of Graphene/Polymer Composites [J].
Du, Jinhong ;
Cheng, Hui-Ming .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2012, 213 (10-11) :1060-1077
[5]   Graphene/Polymer Nanocomposites [J].
Kim, Hyunwoo ;
Abdala, Ahmed A. ;
Macosko, Christopher W. .
MACROMOLECULES, 2010, 43 (16) :6515-6530
[6]   The effects of functionalized graphene nanosheets on the thermal and mechanical properties of epoxy composites for anisotropic conductive adhesives (ACAs) [J].
Kim, Jiwon ;
Yim, Byung-seung ;
Kim, Jong-min ;
Kim, Jooheon .
MICROELECTRONICS RELIABILITY, 2012, 52 (03) :595-602
[7]   Recent advances in graphene based polymer composites [J].
Kuilla, Tapas ;
Bhadra, Sambhu ;
Yao, Dahu ;
Kim, Nam Hoon ;
Bose, Saswata ;
Lee, Joong Hee .
PROGRESS IN POLYMER SCIENCE, 2010, 35 (11) :1350-1375
[8]   Physical and mechanical properties of poly(methyl methacrylate) -functionalized graphene/poly(vinylidine fluoride) nanocomposites Piezoelectric β polymorph formation [J].
Layek, Rama K. ;
Samanta, Sanjoy ;
Chatterjee, Dhruba P. ;
Nandi, Arun K. .
POLYMER, 2010, 51 (24) :5846-5856
[9]   Morphology and electrical properties of graphene-epoxy nanocomposites obtained by different solvent assisted processing methods [J].
Monti, M. ;
Rallini, M. ;
Puglia, D. ;
Peponi, L. ;
Torre, L. ;
Kenny, J. M. .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2013, 46 :166-172
[10]   Raman Spectroscopy and Imaging of Graphene [J].
Ni, Zhenhua ;
Wang, Yingying ;
Yu, Ting ;
Shen, Zexiang .
NANO RESEARCH, 2008, 1 (04) :273-291