Cobalt metal organic framework as an efficient heterogeneous catalyst for the oxidation of alkanes and alkenes

被引：44

作者：

Hamidipour, Lida ^{[1
]}

Farzaneh, Faezeh ^{[1
]}

机构：

[1] Univ Alzahra, Dept Chem, Tehran, Iran

来源：

REACTION KINETICS MECHANISMS AND CATALYSIS | 2013年 / 109卷 / 01期

关键词：

Metal organic framework; Co(II) MOF; 1,3,5-Benzenetricarboxylic acid; Oxidation catalyst; MOLECULAR-OXYGEN; AEROBIC EPOXIDATION; CRYSTAL-STRUCTURES; RECOGNITION; ADAMANTANE; COMPLEXES; DIOXYGEN; STYRENE; OLEFINS; NICKEL;

D O I：

10.1007/s11144-012-0533-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Co(II) metal-organic framework (Co-MOF) containing Co2+ ions, 1,3,5-benzenetricarboxylic acid and N,N-dimethylformamide was prepared and characterized. It was found that the prepared Co-MOF catalyzes the oxidation of alkanes such as fluorene, adamantane, ethylbenzene, diphenylmethane and alkenes such as diphenylethylene, trans-stilbene, cyclohexene, norbornene, styrene and cyclooctene. Details of moderate to excellent conversions and selectivities toward the alkane C-H oxidations and alkene C=C epoxidations will be discussed in this presentation.

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页码：67 / 75

页数：9

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