Iodine Activation of Coordinated White Phosphorus: Formation and Transformation of 1,3-Dihydride-2-iodidecyclotetraphosphane

被引：27

作者：

Barbaro, Pierluigi ^{[2
]}

Bazzicalupi, Carla ^{[1
]}

Peruzzini, Maurizio ^{[2
]}

Costantini, Stefano Seniori ^{[1
]}

Stoppioni, Piero ^{[1
]}

机构：

[1] Univ Firenze, Dipartimento Chim, I-50019 Sesto Fiorentino, Italy

[2] ICCOM CNR, I-50019 Sesto Fiorentino, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 34期

关键词：

hydrolysis; iodine; phosphorus; polyphosphanes; ruthenium; P-4; ACTIVATION; FUNCTIONALIZATION; HYDROLYSIS; COMPLEXES; CAGE; STABILIZATION; AGGREGATION; GENERATION; CHEMISTRY; SILYLENE;

D O I：

10.1002/anie.201203908

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Double stabilization: Previously unknown polyphosphorus compounds are obtained by activation of white phosphorus (P4) coordinated between two CpRu(PPh3)2 moieties with iodine, and subsequent hydrolysis. The polyphosphorus compounds (P4H2I, P4H2, P3H5; see scheme, Cp=cyclopentadienyl) are all stabilized by coordination to two ruthenium centers.

引用

页码：8628 / 8631

页数：4

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