Facile Synthesis of Pentamethylcyclopentadienyl Ruthenium Half-Sandwich Complexes by Naphthalene Displacement

被引：2

作者：

Stone, Jeremy ^{[1
]}

Jago, David ^{[1
]}

Sobolev, Alexandre ^{[2
]}

Spackman, Mark ^{[1
]}

Koutsantonis, George ^{[1
]}

机构：

[1] Univ Western Australia, Sch Mol Sci, 35 Stirling Highway, Perth, WA 6009, Australia

[2] Univ Western Australia, Ctr Microscopy Characterisat & Anal, 35 Stirling Highway, Perth, WA 6009, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2018年 / 71卷 / 04期

基金：

新加坡国家研究基金会;

关键词：

X-RAY-STRUCTURE; METAL-COMPLEXES; CONVENIENT SYNTHESIS; ROOM-TEMPERATURE; DERIVATIVES; LIGANDS; 1,2,3,4,5-PENTAMETHYLCYCLOPENTADIENE; TRANSFORMATIONS; INTERMEDIATE; SUBSTITUTION;

D O I：

10.1071/CH18024

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ruthenium half-sandwich complexes are central in a wide range of diverse applications in the field of organometallic chemistry. As such, exploration of their preparation and reactivity is crucial for development of their chemistry. Herein, we present alternative synthetic methods for the preparation of Cp*Ru(dppm) Cl, Cp*Ru(dppe) Cl, Cp*Ru(dppf) Cl, [Cp*Ru (COD)(MeCN)]BF4, and [Cp*Ru(bpy)(MeCN)]BF4 (dppm = 1,2-bis(diphenylphosphino) methane; dppe = 1,2-bis (diphenylphosphino) ethane; dppf = 1,2-bis(diphenylphosphino) ferrocene; COD = 1,5-cyclooctadiene; bpy = 2,2'-bipyridine), starting from the easily accessible [Cp*Ru(eta(6)-C10H8)]BF4. The single-crystal X-ray structure determinations for [Cp*Ru (COD)(MeCN)]BF4, and [Cp*Ru(bpy)(MeCN)]BF4 are also presented.

引用

页码：289 / 294

页数：6

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