Low Catalyst Loadings in Self-Metathesis of 1-Dodecene

被引：31

作者：

Czaban, Justyna ^{[1
]}

Schertzer, Bryan M. ^{[2
]}

Grela, Karol ^{[1
]}

机构：

[1] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland

[2] Nalco, Naperville, IL 60563 USA

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2013年 / 355卷 / 10期

关键词：

CC bond formation; homogenous catalysis; metathesis; ruthenium; self-metathesis; RING-CLOSING METATHESIS; OLEFIN METATHESIS; RUTHENIUM CATALYSTS; 1-OCTENE; ISOMERIZATION; COMPLEXES; MECHANISM;

D O I：

10.1002/adsc.201200713

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A series of ruthenium catalysts has been screened in the self-metathesis of 1-dodecene with and without the addition of benzoquinones. Many of these catalysts demonstrated excellent selectivity and yields with as low as 10ppm catalyst loading. Reactions have been conducted under decreased pressure or under argon bubbling, which caused a tremendous increase in yield and selectivity of the examined process.

引用

页码：1997 / 2006

页数：10

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