Two dimensional nuclear magnetic resonance analysis of bis(2,2′-bipyridine)(2,2′-bipyridine-4,4′-dicarboxylic acid)ruthenium(II) hexafluorophosphate

被引：0

作者：

Wang, P ^{[1
]}

Shu, HM ^{[1
]}

Zhu, GY ^{[1
]}

Zhou, ZA ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, Electroanalyt Chem Lab, Changchun 130022, Peoples R China

来源：

CHINESE JOURNAL OF ANALYTICAL CHEMISTRY | 1999年 / 27卷 / 09期

关键词：

bis (2,2 '-bipyridine) (2,2 '-bipyridine-4, 4 '-dicarboxylic acid) ruthenium(II); hexafluorophosphate; two dimensional nuclear magnetic resonance;

D O I：

暂无

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The H-1 and C-13 nuclear magnetic resonance(NMR) spectra are reported for bis(2, 2'-bipyridine)(2, 2'-bipyridine-,4,4'-dicarboxylic acid) ruthenium(II) hexafluoruphosphate that has been used as a tagged molecule of electrochemiluminescent immunoassay. Because of the effect of Ru atom on ligands, it is difficult to assign its NMR spectra. BS' means of two dimensional H-1-H-1 COSY and H-1-C-13 COSY techniques, the H-1 and C-13 NMR spectra of bis (2, 2'-bipylidine) (2, 2'-bipyridine-4, 4-dicarboxylic acid) ruthenium(II) hexafluorophosphate are assigned completely. This provides a basis for NMR characterization of the nerv similar tagged molecules.

引用

页码：1043 / 1046

页数：4