Sudan I monitoring as a hazardous azo dye using an electroanalytical tool amplified with NiO/SWCNTs-ionic liquid catalysts

被引:11
作者
Arjmandi, Javid [1 ]
Shahidi, Seyed-Ahmad [1 ]
Ghorbani-HasanSaraei, Azade [1 ]
Limooei, Mohammad Bagher [2 ]
Raeisi, Shahram Naghizadeh [1 ]
机构
[1] Islamic Azad Univ, Dept Food Sci & Technol, Ayatollah Amoli Branch, Amol, Iran
[2] Islamic Azad Univ, Dept Mat Sci & Engn, Ayatollah Amoli Branch, Amol, Iran
关键词
Sudan I analysis; NiO; SWCNTs nanocomposite; Modified sensor; Nano; -catalyst; SENSOR; ELECTRODE; NANOPARTICLES; METHYLDOPA; STRATEGY;
D O I
10.1016/j.chemosphere.2022.136673
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Sudan I is an azo dye that causes cancer and is not allowed to be used in food products. The current study focused on the design and manufacture of an electrochemical sensor modified with NiO/SWCNTs, as a nano-catalyst, and 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (1H3MIbTMI), as an ionic liquid binder, to monitor Sudan I as azo additive dyes in various food samples. The modified carbon paste electrode (CPE/NiO/ SWCNTs/1H3MIbTMI) offered superior electrochemical performance metrics as an analytical sensor to detect trace levels of Sudan I within the concentration range of 1.0 nM-250 mu M. The limit of detection was determined as 0.3 nM by the differential pulse voltammetric (DPV) technique. The proposed CPE/NiO/SWCNTs/1H3MIbTMI can be put forward to be employed as an analytical instrument for sensing Sudan I in various culinary sauces, including chili, tomato, and strawberry sauces. The obtained recovery range was determined as 97.6%-104.35%. These findings demonstrated the effectiveness of the newly created material and its potential for usage as a novel analytical instrument.
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页数:6
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