A novel cement-based hybrid material

被引:95
作者
Nasibulin, Albert G. [1 ,2 ]
Shandakov, Sergey D. [1 ,2 ,3 ]
Nasibulina, Larisa I. [1 ,2 ]
Cwirzen, Andrzej [4 ]
Mudimela, Prasantha R. [1 ,2 ]
Habermehl-Cwirzen, Karin [4 ]
Grishin, Dmitrii A. [5 ]
Gavrilov, Yuriy V. [5 ]
Malm, Jari E. M. [6 ]
Tapper, Unto [7 ]
Tian, Ying [1 ,2 ]
Penttala, Vesa [4 ]
Karppinen, Maarit J. [6 ]
Kauppinen, Esko I. [1 ,2 ,8 ]
机构
[1] Aalto Univ, Dept Appl Phys, FIN-02150 Espoo, Finland
[2] Aalto Univ, Ctr New Mat, FIN-02150 Espoo, Finland
[3] Kemerovo State Univ, Dept Phys, Lab Carbon NanoMat, Kemerovo 650043, Russia
[4] Aalto Univ, Fac Engn & Architecture, Lab Bldg Mat Technol, FIN-02150 Espoo, Finland
[5] Mendeleev Univ Chem Technol, Moscow 125190, Russia
[6] Aalto Univ, Dept Chem, Inorgan Chem Lab, FIN-02150 Espoo, Finland
[7] VTT Tech Res Ctr Finland, Espoo 02044, Finland
[8] VTT Biotechnol, Espoo 02044, Finland
基金
芬兰科学院;
关键词
WALLED CARBON NANOTUBES; MATRIX COMPOSITES; GROWTH; MONOXIDE; CATALYSTS; MICROSTRUCTURE; TEMPERATURE; BEHAVIOR; OXIDE;
D O I
10.1088/1367-2630/11/2/023013
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Carbon nanotubes (CNTs) and carbon nanofibers (CNFs) are known to possess exceptional tensile strength, elastic modulus and electrical and thermal conductivity. They are promising candidates for the next-generation high-performance structural and multi-functional composite materials. However, one of the largest obstacles to creating strong, electrically or thermally conductive CNT/CNF composites is the difficulty of getting a good dispersion of the carbon nanomaterials in a matrix. Typically, time-consuming steps of purification and functionalization of the carbon nanomaterial are required. We propose a new approach to grow CNTs/CNFs directly on the surface of matrix particles. As the matrix we selected cement, the most important construction material. We synthesized in a simple one-step process a novel cement hybrid material (CHM), wherein CNTs and CNFs are attached to the cement particles. The CHM has been proven to increase 2 times the compressive strength and 40 times the electrical conductivity of the hardened paste, i.e. concrete without sand.
引用
收藏
页数:11
相关论文
共 37 条
[1]   Narrow (n,m)-distribution of single-walled carbon nanotubes grown using a solid supported catalyst [J].
Bachilo, SM ;
Balzano, L ;
Herrera, JE ;
Pompeo, F ;
Resasco, DE ;
Weisman, RB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (37) :11186-11187
[2]  
Bae EJ, 2002, ADV MATER, V14, P277, DOI 10.1002/1521-4095(20020219)14:4<277::AID-ADMA277>3.0.CO
[3]  
2-A
[4]  
Bae J, 2002, MACROMOL CHEM PHYS, V203, P2196, DOI 10.1002/1521-3935(200211)203:15<2196::AID-MACP2196>3.0.CO
[5]  
2-U
[6]   Large-area synthesis of carbon nanofibres at room temperature [J].
Boskovic, BO ;
Stolojan, V ;
Khan, RUA ;
Haq, S ;
Silva, SRP .
NATURE MATERIALS, 2002, 1 (03) :165-168
[7]   Nanotube composites - A recipe for strength [J].
Calvert, P .
NATURE, 1999, 399 (6733) :210-211
[8]   Growth of carbon nanotubes by catalytic decomposition of CH4 or CO on a Ni-MgO catalyst [J].
Chen, P ;
Zhang, HB ;
Lin, GD ;
Hong, Q ;
Tsai, KR .
CARBON, 1997, 35 (10-11) :1495-1501
[9]   Single-wall nanotubes produced by metal-catalyzed disproportionation of carbon monoxide [J].
Dal, HJ ;
Rinzler, AG ;
Nikolaev, P ;
Thess, A ;
Colbert, DT ;
Smalley, RE .
CHEMICAL PHYSICS LETTERS, 1996, 260 (3-4) :471-475
[10]  
Dresselhaus M.S., 1996, SCI FULLERENES NANOT