Nickel-catalyzed silaboration of small-ring vinylcycloalkanes:: Regio- and stereoselective (E)-allylsilane formation via C-C bond cleavage

被引：51
作者：
Suginome, M [1 ]
Matsuda, T
Yoshimoto, T
Ito, Y
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Kyoto 6068501, Japan
[2] JST, Japan Sci & Technol Corp, PRESTO, Kyoto 6068501, Japan
来源：
ORGANOMETALLICS | 2002年 / 21卷 / 08期
关键词：
D O I：
10.1021/om020007k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Vinylcyclopropanes and vinylcyclobutanes undergo regio- and stereoselective reaction with silylborane in the presence of nickel catalysts, giving (omega-borylalkyl)-substituted (E)-allylsilanes via cleavage of the carbon-carbon sigma-bond in the rings.
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收藏
页码：1537 / 1539
页数：3
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