How Fast is a Fast Equilibrium? A New View of Reversible Reactions

被引：13

作者：

Baleizao, Carlos ^{[1
,2
]}

Berberan-Santos, Mario N. ^{[1
,2
]}

机构：

[1] Univ Tecn Lisboa, CQFM Ctr Quim Fis Mol, P-1049001 Lisbon, Portugal

[2] Univ Tecn Lisboa, IN Inst Nanosci & Nanotechnol, Inst Super Tecn, P-1049001 Lisbon, Portugal

来源：

CHEMPHYSCHEM | 2009年 / 10卷 / 01期

关键词：

fluorescence; enzyme catalysis; excited-state proton transfer; FRET; kinetics; DELAYED FLUORESCENCE; KINETICS; C-70;

D O I：

10.1002/cphc.200800350

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Reversible reactions are described in terms of kinetic cycles. From this description, two useful parameters arise: 1) average cycle duration and 2) average number of cycles. The latter applies to cycles with at least one unstable species. These parameters allow answering the question "How fast is a fast equilibrium?" in absothe lute and in relative terms, respectively. The general interest of approach is demonstrated by application to reactions drawn from several areas: Acid-base equilibria, enzyme kinetics, excited-state proton transfer, thermally activated delayed fluorescence, monomer-excimer kinetics and homo-FRET

引用

页码：199 / 205

页数：7

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