Application of novel hierarchical niobium-containing zeolites for synthesis of alkyl lactate and lactic acid

被引：24

作者：

Feliczak-Guzik, Agnieszka ^{[1
,2
]}

Sprynskyy, Myroslav ^{[1
]}

Nowak, Izabela

Jaroniec, Mietek ^{[2
,3
]}

Buszewski, Boguslaw ^{[1
]}

机构：

[1] Nicolaus Copernicus Univ Torun, Fac Chem, 7 Gagarina Str, PL-87100 Torun, Poland

[2] Adam Mickiewicz Univ, Fac Chem, 89b Umultowska Str, PL-61614 Poznan, Poland

[3] Kent State Univ, Dept Chem & Biochem, Kent, OH 44242 USA

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2018年 / 516卷

关键词：

Hierarchical zeolites containing niobium; Lactic acid; Alkyl lactate; Biomass; Dihydroxyactetone (DHA); CATALYTIC PERFORMANCE; MESOPORE SIZE; CONVERSION; DIHYDROXYACETONE; GLYCEROL;

D O I：

10.1016/j.jcis.2018.01.090

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Novel hierarchical niobium-containing zeolites were synthesized for the first time and applied for isomerization of dihydroxyactetone to alkyl lactate and lactic acid (95-97% yield). These materials possess secondary mesoporosity, thus facilitating access to active sites of the material by larger reagent molecules, preserving acidity and crystallinity of the zeolites. (C) 2018 Elsevier Inc. All rights reserved.

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收藏

页码：379 / 383

页数：5

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