Superplastic nanocrystalline ceramics at room temperature and high strain rates

被引:27
作者
Zhang, J. Y. [1 ]
Sha, Z. D. [1 ]
Branicio, P. S. [1 ]
Zhang, Y. W. [1 ]
Sorkin, V. [1 ]
Pei, Q. X. [1 ]
Srolovitz, D. J. [2 ,3 ]
机构
[1] Agcy Sci Technol & Res, Inst High Performance Comp, Singapore 138632, Singapore
[2] Univ Penn, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
[3] Univ Penn, Dept Mech Engn & Appl Mech, Philadelphia, PA 19104 USA
关键词
Nanostructured ceramics; Superplasticity; High strain rates; Grain size effect; Silicon carbide; SIC NANOWIRES; MOLECULAR-DYNAMICS; PLASTIC-FLOW; DIFFUSION; DUCTILITY; CARBIDE; CREEP;
D O I
10.1016/j.scriptamat.2013.06.017
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Tensile-loading molecular dynamics simulations show that nanocrystalline SiC not only becomes ductile, but can be superplastically deformed at room temperature when grain sizes are reduced to d similar to 2 nm. The calculated strain rate sensitivity, 0.67, implies a superplastic ceramic able to attain strains of up to 1000% at room temperature and typical strain rates (similar to 10(-2) s(-1)). The origin of the superplasticity is linked to an unusually steep rise in creep rate to 10(6) s(-1) for d = 2 nm. The results explain recent observations in SiC nanowires and suggest novel opportunities for structural ceramics. (C) 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:525 / 528
页数:4
相关论文
共 31 条
[1]   HIGH-STRENGTH CERAMICS THROUGH COLLOIDAL CONTROL TO REMOVE DEFECTS [J].
ALFORD, NM ;
BIRCHALL, JD ;
KENDALL, K .
NATURE, 1987, 330 (6143) :51-53
[2]   FLAW-INSENSITIVE CERAMICS [J].
BENNISON, SJ ;
PADTURE, NP ;
RUNYAN, JL ;
LAWN, BR .
PHILOSOPHICAL MAGAZINE LETTERS, 1991, 64 (04) :191-195
[3]   STRATEGIES TO DEFEAT BRITTLENESS [J].
CAHN, RW .
NATURE, 1988, 332 (6160) :112-113
[4]   Sintering, structure, and mechanical properties of nanophase SiC: A molecular-dynamics and neutron scattering study [J].
Chatterjee, A ;
Kalia, RK ;
Nakano, A ;
Omeltchenko, A ;
Tsuruta, K ;
Vashishta, P ;
Loong, CK ;
Winterer, M ;
Klein, S .
APPLIED PHYSICS LETTERS, 2000, 77 (08) :1132-1134
[6]   SOLVENT-ACCESSIBLE SURFACES OF PROTEINS AND NUCLEIC-ACIDS [J].
CONNOLLY, ML .
SCIENCE, 1983, 221 (4612) :709-713
[7]   Analytical potential for atomistic simulations of silicon, carbon, and silicon carbide [J].
Erhart, P ;
Albe, K .
PHYSICAL REVIEW B, 2005, 71 (03)
[8]   Microstructure and tribological properties of advanced carbon/silicon carbide aircraft brake materials [J].
Fan, Shangwu ;
Zhang, Litong ;
Xu, Yongdong ;
Cheng, Laifei ;
Tian, Guanglai ;
Ke, Shaochang ;
Xu, Fang ;
Liu, Haiping .
COMPOSITES SCIENCE AND TECHNOLOGY, 2008, 68 (14) :3002-3009
[9]   Triple junction diffusion and plastic flow in fine-grained materials [J].
Fedorov, AA ;
Gutkin, MY ;
Ovid'ko, IA .
SCRIPTA MATERIALIA, 2002, 47 (01) :51-55
[10]   Low-temperature in situ large strain plasticity of ceramic SiC nanowires and its atomic-scale mechanism [J].
Han, X. D. ;
Zhang, Y. F. ;
Zheng, K. ;
Zhang, X. N. ;
Zhang, Z. ;
Hao, Y. J. ;
Guo, X. Y. ;
Yuan, J. ;
Wang, Z. L. .
NANO LETTERS, 2007, 7 (02) :452-457