Assessing the guest-accessible volume in MOFs using two-photon fluorescence microscopy

被引：35
作者：
Shin, Sung Min [1 ]
Lee, Mi Sun [1 ]
Han, Ji Hee [1 ]
Jeong, Nakcheol [1 ]
机构：
[1] Korea Univ, Dept Chem, Seoul 136701, South Korea
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 03期
关键词：
CRYSTAL-STRUCTURES; METHANE; DESIGN;
D O I：
10.1039/c3cc44008g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The assessment of guest-accessible volume in MOFs can be reliably done by using two-photon confocal fluorescence microscopy (TPM) with a tool-box of dyes with a wide range of sizes. It would be applicable to any porous materials, whose single-crystal structures are not available, or non-crystalline materials.
引用
收藏
页码：289 / 291
页数：3
相关论文
共 19 条
[1]  
[Anonymous], 2010, ALL DAT PROC WAS PER
[2]   Postsynthetic Methods for the Functionalization of Metal-Organic Frameworks [J].
Cohen, Seth M. .
CHEMICAL REVIEWS, 2012, 112 (02) :970-1000
[3]   Porous, crystalline, covalent organic frameworks [J].
Côté, AP ;
Benin, AI ;
Ockwig, NW ;
O'Keeffe, M ;
Matzger, AJ ;
Yaghi, OM .
SCIENCE, 2005, 310 (5751) :1166-1170
[4]   Design of new materials for methane storage [J].
Düren, T ;
Sarkisov, L ;
Yaghi, OM ;
Snurr, RQ .
LANGMUIR, 2004, 20 (07) :2683-2689
[5]   Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].
Eddaoudi, M ;
Kim, J ;
Rosi, N ;
Vodak, D ;
Wachter, J ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2002, 295 (5554) :469-472
[6]   Review and Analysis of Molecular Simulations of Methane, Hydrogen, and Acetylene Storage in Metal-Organic Frameworks [J].
Getman, Rachel B. ;
Bae, Youn-Sang ;
Wilmer, Christopher E. ;
Snurr, Randall Q. .
CHEMICAL REVIEWS, 2012, 112 (02) :703-723
[7]  
Han S., 2012, ANGEW CHEM INT EDIT, V51, P1
[8]   Deep tissue two-photon microscopy [J].
Helmchen, F ;
Denk, W .
NATURE METHODS, 2005, 2 (12) :932-940
[9]   Asymmetric catalytic reactions by NbO-type chiral metal-organic frameworks [J].
Jeong, Kyung Seok ;
Go, Yong Bok ;
Shin, Sung Min ;
Lee, Suk Joong ;
Kim, Jaheon ;
Yaghi, Omar M. ;
Jeong, Nakcheol .
CHEMICAL SCIENCE, 2011, 2 (05) :877-882
[10]   Near achiral metal-organic frameworks from conformationally flexible homochiral ligands resulted by the preferential formation of pseudo-inversion center in asymmetric unit [J].
Jeong, Kyung Seok ;
Lee, Bo Hyung ;
Li, Qiaowei ;
Choi, Sang Beom ;
Kim, Jaheon ;
Jeong, Nakcheol .
CRYSTENGCOMM, 2011, 13 (05) :1277-1279
12