Complexes of Co(II), Ni(II), Cu(II), and Pd(II) with Sulfametrole-Cyclodiphosph(V)azane Derivatives

被引:6
|
作者
Alaghaz, A. M. A. [1 ]
机构
[1] Al Azhar Univ Boys, Fac Sci, Dept Chem, Cairo, Egypt
关键词
complexes; Cyclodiphosph(V)azane; dithiolate; sulfametrole;
D O I
10.1080/10426500802016661
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Novel [1,3-di-[N1-4-methoxy-1,2,5-thiadiazole-3-yl-sulfanilamide(sulfametrole)]2,,4-bis-[1,3-dithiole-2-thione-4,5-dithiolate]-2 ',4 '-dichlorocyclodiphosph(V)azane] (III), was prepared and their coordinating behavior towards the metal ions Co(II), Ni(II), Cu(II), and Pd(II) was studied. The structures of the isolated products are proposed based on elemental analyses, IR, UV, H-1, and P-31 NMR, ESR, magnetic susceptibility, molar ratio, conductometric titration and electrical conductivity measurements. The prepared complexes showed high to moderate bactericidal activity compared with the ligand.
引用
收藏
页码:2807 / 2826
页数:20
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