Engineered Magnetic Shape Anisotropy in BiFeO3-CoFe2O4 Self-Assembled Thin Films

被引:71
作者
Wang, Zhiguang [1 ]
Li, Yanxi [1 ]
Viswan, Ravindranath [1 ]
Hu, Bolin [2 ]
Harris, Vincent G. [2 ]
Li, Jiefang [1 ]
Viehland, Dwight [1 ]
机构
[1] Virginia Polytech Inst & State Univ, Dept Mat Sci & Engn, Blacksburg, VA 24061 USA
[2] Northeastern Univ, Dept Elect & Comp Engn, Boston, MA 02115 USA
关键词
BiFeO3-CoFe2O4; self-assembled thin film; magnetic shape anisotropy; GRAIN-SIZE DEPENDENCE; ARRAYS; FIELD;
D O I
10.1021/nn4003506
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report growth of various phase architectures of self-assembled BiFeO3-CoFe2(O4) (BFO-CFO) thin films on differently oriented SrTiO3 (STO) substrates. CFO forms segregated square, stripe, and triangular nanopillars embedded in a coherent BFO matrix on (001)-, (110)-, and (111)-oriented STO substrates, respectively. Nanostructures with an aspect ratio of up to 5:1 with a prominent magnetic anisotropy were obtained on both (001) and (110) STO along out-of-plane and in-plane directions. Magnetic easy axis rotation from in-plane to out-of-plane directions was realized through aspect ratio control. An intractable in-plane anisotropy was fixed in CFO on (111) STO due to the triangular shape of the ferromagnetic phase nanopillars. These studies established a detailed relationship of magnetic anisotropy with specific shape and dimensions of ordered magnetic arrays. The results suggest a way to effectively control the magnetic anisotropy in patterned ferromagnetic oxide arrays with tunable shape, aspect ratio, and elastic strain conditions of the nanostructures.
引用
收藏
页码:3447 / 3456
页数:10
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