Synthesis and Photocatalytic Properties of ZnWO4 Nanocrystals via a Fast Microwave-Assisted Method

被引：35
作者：
Yan, Jing [1 ]
Shen, Yanhua [1 ]
Li, Feng [1 ]
Li, Taohai [1 ]
机构：
[1] Xiangtan Univ, Coll Chem, Minist Educ, Key Lab Environm Friendly Chem & Applicat, Xiangtan 411105, Peoples R China
来源：
SCIENTIFIC WORLD JOURNAL | 2013年
关键词：
METAL TUNGSTATES; NANOSIZED BI2WO6; FABRICATION; PHOTOLUMINESCENCE; LUMINESCENCE; DEGRADATION; POWDERS; CD;
D O I：
10.1155/2013/458106
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
High crystallinity of ZnWO4 nanoparticles has been successfully synthesized via a highly effective and environmentally friendly microwave route by controlling the reaction time and temperature. The products were characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), and Fourier infrared spectrum (FT-IR). The crystallinity was enhanced with the increase of the reaction temperature and time. The photocatalytic activities of ZnWO4 nanocrystals were evaluated by testing the photodegradation of rhodamine B (RhB) dye under ultraviolet (UV) light irradiation. The results indicated that as-prepared ZnWO4 w as highly effective for the degradation of RhB. The degradation rate of RhB reached 98.01% after 6 h of UV illumination.
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页数：8
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共 36 条
[1]   Epitaxial growth of ZnO nanocrystals at ZnWO4(0 1 0) cleaved surface [J].
Atuchin, V. V. ;
Galashov, E. N. ;
Kozhukhov, A. S. ;
Pokrovsky, L. D. ;
Shlegel, V. N. .
JOURNAL OF CRYSTAL GROWTH, 2011, 318 (01) :1147-1150
[2]   Structural and Electronic Properties of ZnWO4(010) Cleaved Surface [J].
Atuchin, Victor V. ;
Galashov, Evgeny N. ;
Khyzhun, Oleg Yu ;
Kozhukhov, Anton S. ;
Pokrovsky, Lel D. ;
Shlegel, Vladimir N. .
CRYSTAL GROWTH & DESIGN, 2011, 11 (06) :2479-2484
[3]   Radioactive contamination of ZnWO4 crystal scintillators [J].
Belli, P. ;
Bernabei, R. ;
Cappella, F. ;
Cerulli, R. ;
Danevich, F. A. ;
Dubovik, A. M. ;
d'Angelo, S. ;
Galashov, E. N. ;
Grinyov, B. V. ;
Incicchitti, A. ;
Kobychev, V. V. ;
Laubenstein, M. ;
Nagornaya, L. L. ;
Nozzoli, F. ;
Poda, D. V. ;
Podviyanuk, R. B. ;
Polischuk, O. G. ;
Prosperi, D. ;
Shlegel, V. N. ;
Tretyak, V. I. ;
Tupitsyna, I. A. ;
Vasiliev, Ya. V. ;
Vostretsov, Yu. Ya. .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 2011, 626 :31-38
[4]   A facile microwave solvothermal process to synthesize ZnWO4 nanoparticles [J].
Bi, Jinhong ;
Wu, Ling ;
Li, Zhaohui ;
Ding, Zhengxin ;
Wang, Xuxu ;
Fu, Xianzhi .
JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 480 (02) :684-688
[5]   Optical spectra and energy levels of the Cr3+ ions in MWO4 (M = Mg, Zn, Cd) and MgMoO4 crystals [J].
Cavalli, E. ;
Belletti, A. ;
Brik, M. G. .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2008, 69 (01) :29-34
[6]   Low-temperature synthesis of metal tungstates nanocrystallites in ethylene glycol [J].
Chen, D ;
Shen, GZ ;
Tang, KB ;
Zheng, HG ;
Qian, YT .
MATERIALS RESEARCH BULLETIN, 2003, 38 (14) :1783-1789
[7]   Fabrication of nanocrystalline ZnWO4 with different morphologies and sizes via hydrothermal route [J].
Chen, SJ ;
Zhou, JH ;
Chen, XT ;
Li, J ;
Li, LH ;
Hong, JM ;
Xue, ZL ;
You, XZ .
CHEMICAL PHYSICS LETTERS, 2003, 375 (1-2) :185-190
[8]   Photoluminescence properties of ZnWO4:Eu3+ nanocrystals prepared by a hydrothermal method [J].
Dai, Qilin ;
Song, Hongwei ;
Bai, Xue ;
Pan, Guohui ;
Lu, Shaozhe ;
Wang, Tie ;
Ren, Xinguang ;
Zhao, Haifeng .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (21) :7586-7592
[9]   Synthesis, characterization and photocatalytic properties of nanosized Bi2WO6, PbWO4 and ZnWO4 catalysts [J].
Fu, Hongbo ;
Pan, Chengsi ;
Zhang, Liwu ;
Zhu, Yongfa .
MATERIALS RESEARCH BULLETIN, 2007, 42 (04) :696-706
[10]   Photocatalytic properties of nanosized Bi2WO6 catalysts synthesized via a hydrothermal process [J].
Fu, Hongbo ;
Zhang, Liwu ;
Yao, Wenqing ;
Zhu, Yongfa .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 66 (1-2) :100-110
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