Influence of Nd3+ concentration on up-conversion fluorescence colour in YVO4 co-doped with Ho3+, Yb3+ and Nd3+ ions

被引:19
作者
Sobczyk, Marcin [1 ]
机构
[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
关键词
Up-conversion fluorescence; Nd3+/Ho3+/Yb3+ co-doped YVO4; Vanadates; Emission colour; INFRARED RADIATION; CRYSTALS; EMISSION; YTTERBIUM; HOLMIUM;
D O I
10.1016/j.matlet.2012.08.026
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Influence of Nd3+ concentration on up-conversion fluorescence colour in YVO4 triple doped with Ho3+, Yb3+ and Nd3+ ions excited by 980 nm laser diode was investigated. A serials of NdxHo0.02 Yb0.05Y0.93-xVO4 (where x=0, 0.25, 0.5, 0.75 and 1 at%) crystalline materials were synthesised by a solid state reaction. Excitation in the F-2(5/2) bands of Yb3+ produced a strong red and a weaker green emissions at 300 K for Ho3+,Yb3+:YVO4 whereas for Ho3+,Yb3+,Nd3+:YVO4 a strong green emission was observed. Concentration dependence studies indicated that Nd3+ concentrations had significant influences on up-conversion mechanisms and emission colour. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:86 / 88
页数:3
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