A dual-channel fluorescence-enhanced sensor for aluminum ions based on photoinduced electron transfer and excimer formation

被引:64
作者
Lin, Weiying [1 ]
Yuan, Lin [1 ]
Feng, Jianbo [1 ]
机构
[1] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemobiosensing & Chemometr, Changsha 410082, Hunan, Peoples R China
关键词
sensors; aluminum; fluorescence; coumarins;
D O I
10.1002/ejoc.200800327
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Sensor 1 was developed as the first example of a fluorescence-enhanced Al3+ sensor with unique dual-channel emissions. The addition of Al3+ to 1 elicits a large fluorescence enhancement by inhibition of a quenching Photoinduced electron-transfer (PET) channel and also a dramatic fluorescence enhancement due to promotion of an emissive excimer channel formation, The dual-channel fluorescence-enhanced response of the sensor contributes to its high sensitivity and selectivity. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).
引用
收藏
页码:3821 / 3825
页数:5
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