Electrochemical study of polymethacrylonitrile electrolytes -: Comparative investigation of polynitriles electrochemical stability through model molecules.: Part II

被引：11

作者：

Chaix, N ^{[1
]}

Alloin, F ^{[1
]}

Bélières, JP ^{[1
]}

Saunier, J ^{[1
]}

Sanchez, JY ^{[1
]}

机构：

[1] UJF, CNRS, UMR 5631, LEPMI,INPG,ENSEEG, F-38402 St Martin Dheres, France

来源：

ELECTROCHIMICA ACTA | 2002年 / 47卷 / 08期

关键词：

polymethacrylonitrile; polymer electrolyte; trimethylacetonitrile; isobutyronitrile and electrochemical stability;

D O I：

10.1016/S0013-4686(01)00853-2

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The replacement of polyacrylonitrile by polymethacrylonitrile is expected to provide an improvement of the electrochemical stability in reduction of the plasticized polymer electrolytes. In addition to the investigation on the polymer electrolyte, a comparative study of polymethacrylonitrile and polyacrylonitrile, performed through their respective model repeat unit, i.e. trimethylacetonitrile and isobutyronitrile confirms the stability improvement obtained by replacing polyacrylonitrile tertiary hydrogen by a methyl in polymethacrylonitrile. (C) 2002 Published by Elsevier Science Ltd.

引用

页码：1327 / 1334

页数：8

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