Three-dimensional Hemidirected Mixed-ligand Lead(II) Coordination Polymer, [Pb2(bpa)2(SCN)3(NO3)]n (bpa=1,2-di(4-pyridyl)ethane)

被引：9

作者：

Abedini, Jafar ^{[2
]}

Morsali, Ali ^{[1
]}

Zeller, Matthias ^{[3
]}

机构：

[1] Tarbiat Modares Univ, Fac Sci, Dept Chem, Tehran, Iran

[2] Payame Noor Univ, Dept Sci, Abhar, Zanjan, Iran

[3] Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2008年 / 634卷 / 14期

关键词：

Lead; 1,2-di(4-pyridyl)ethane; Coordination polymer;

D O I：

10.1002/zaac.200800333

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 3D hemidirected mixed-ligand lead(II) coordination polymer with the ligand 1,24(4-pyridyl)ethane bpa) and the two metal coordinated anions nitrate and thiocyanate, [Pb-2(bpa)(2)(SCN)(3)(NO3)](n) (1), has been synthesized and characterized by CHN elemental analysis, IR-, H-1- and C-13 NMR spectroscopy. The single crystal X-ray data of compound 1 show that the complex is a three-dimensional coordination polymer with two different Pb atoms with stereoactive electron lone pairs and six- and five-coordinate hemidirected geometries, respectively.

引用

页码：2659 / 2662

页数：4

共 50 条

[1] Novel homochiral holodirected three-dimensional lead(II) coordination polymer, [Pb2(μ-bpa)3(μ-NO3)2(NO3)2]n:: Spectroscopic, thermal fluorescence and structural studies
Aslani, Alireza
Morsali, Ali
Zeller, Matthias
SOLID STATE SCIENCES, 2008, 10 (07) : 854 - 858
[2] A coordination polymer based on twofold interpenetrating three-dimensional four-connected nets of 42638 topology, [CuSCN(bpa)] [bpa=1,2-bis(4-pyridyl)ethane]
Wang, QM
Guo, GC
Mak, TCW
CHEMICAL COMMUNICATIONS, 1999, (18) : 1849 - 1850
[3] Two-dimensional holodirected lead(II) coordination polymer, [Pb(μ-bpp)(μ-SCN)2]n (bpp=1,3-di(4-pyridyl)propane)
Taheri, Syavash
Mojidov, Ajdar
Morsali, Ali
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2007, 633 (11-12): : 1949 - 1951
[4] Structural analysis and magnetic properties of the 2-D compounds [M(N3)2(bpa)]n (M = Mn, Co or Ni; bpa = 1,2-bis(4-pyridyl)ethane)
Hernández, ML
Barandika, MG
Urtiaga, MK
Cortés, R
Lezama, L
Arriortua, MI
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (01): : 79 - 84
[5] Synthesis and spectroscopic studies of mixed-ligand complexes of lead(II) hexafluoroacetylacetonate including the crystal structure of [Pb2(phen)4(hfa)2(-NO3)2]
Marandi, Farzin
Chantrapromma, Suchada
Fun, Hoong-Kun
JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (02) : 249 - 256
[6] Density Functional Study on Spin-crossover Phenomena of Assembled Complexes, [Fe(NCX)2(bpa)2]n (X=S, Se, and BH3; bpa: 1,2-bis(4-pyridyl)ethane)
Kaneko, Masashi
Tokinobu, Satoshi
Nakashima, Satoru
CHEMISTRY LETTERS, 2013, 42 (11) : 1432 - 1434
[7] Supramolecular isomerism in coordination polymers: Conformational freedom of ligands in [Co(NO3)(2)(1,2-bis(4-pyridyl)ethane)(1.5)](n)
Hennigar, TL
MacQuarrie, DC
Losier, P
Rogers, RD
Zaworotko, MJ
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (09) : 972 - 973
[8] Supramolecular Isomerism in Coordination Polymers: Conformational Freedom of Ligands in [Co(NO3)2(1,2-bis(4-pyridyl)ethane)1.5] n
Hennigar, Tracy L.
MacQuarrie, Donald C.
Losier, Pierre
Rogers, Robin D.
Zaworotko, Michael J.
Angewandte Chemie (International Edition in English), 1997, 36 (09): : 972 - 973
[9] Spiral Assembly of the 1D Chain Sheet of Fe(NCBH3)2(bpa)2•(biphenyl) (bpa=1,2-bis(4-pyridyl)ethane) and its Stepwise Spin-Crossover Phenomenon
Nakashima, Satoru
Morita, Takaki
Inoue, Katsuya
Hayami, Shinya
POLYMERS, 2012, 4 (01) : 880 - 888
[10] [Pb2(2,2′-bipy)2(μ-4,4′-bipy)(NO3)4]:: A novel hemidirected dimeric mixed-ligands lead(II) complex extended in holodirected two-dimensional polymer by weak Pb-Onitrate interactions
Soudi, AA
Marandi, F
Morsali, A
Zhu, LG
INORGANIC CHEMISTRY COMMUNICATIONS, 2005, 8 (09) : 773 - 776

← 1 2 3 4 5 →