Synthesis and characterization of (η5-cyclopentadienyl)(η5-(1-(η5-cyclopentadienyl))-2-phenyl-3-ethyl-1-nickelaindenyl) nickel, a new nickelacyclic analogue of nickelocene

被引：7
|
作者：
Buchalski, P
Pasynkiewicz, S
Pietrzykowski, A
Pilka, A
Suwinska, K
机构：
[1] Warsaw Univ Technol, Fac Chem, PL-00662 Warsaw, Poland
[2] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 04期
关键词：
nickel; alkali metals; clusters; cyclopentadienyl; metallacyclic compounds;
D O I：
10.1016/j.inoche.2006.01.006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new nickelacyclic compound (eta(5)-cyclopentadienyl)(eta(5)-(1-(eta(5)-cyclopentadienyl))-2-phenyl-3-ethyl-1-nickelaindenyl)nickel was synthesised in the reaction of (E)-1-lithio-1-phenyl-2-(2'-lithiophenyl)ethane with nickelocene. The compound was characterised by high resolution mass spectrometry, magnetic moment determination and X-ray single crystal analysis. It crystallises from hexane/THF mixture in the monoclinic crystal system and the P2(1)/n space group. (c) 2006 Elsevier B.V. All rights reserved.
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收藏
页码：375 / 378
页数：4
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