Detection of trace elements in ice and water by laser-induced breakdown spectroscopy

被引：94

作者：

Sobral, H. ^{[1
]}

Sangines, R. ^{[1
]}

Trujillo-Vazquez, A. ^{[1
]}

机构：

[1] Univ Nacl Autonoma Mexico, Ctr Ciencias Aplicadas & Desarrollo Tecnol, Mexico City 04510, DF, Mexico

来源：

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY | 2012年 / 78卷

关键词：

LIBS in liquids; Trace analysis; Plasma characterization; QUANTITATIVE-ANALYSIS; AQUEOUS-SOLUTIONS; INDUCED PLASMA; WASTE-WATER; HEAVY-METALS; TOXIC METALS; SINGLE-PULSE; WEAR METALS; LIBS; PLANT;

D O I：

10.1016/j.sab.2012.09.005

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

In this work the detection sensitivity of Cu, Mg, Pb, Hg, Cd, Cr and Fe traces in water and ice samples has been investigated under the same experimental conditions by using laser-induced breakdown spectroscopy. Plasmas were generated by focusing the fundamental output of a Nd: YAG laser on target surfaces. Limits of detection in ice were found to be six times lower on average compared to measurements from the liquid. The evolution of the plasma electron temperature was similar for both, solid and liquid samples; while the initial electron density was higher in the plasma produced on the solid target. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：62 / 66

页数：5

共 42 条

[1] Laser-induced breakdown spectroscopy at a water/gas interface: A study of bath gas-dependent molecular species [J].

Adamson, M. ;

Padmanabhan, A. ;

Godfrey, G. J. ;

Rehse, S. J. .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2007, 62 (12) :1348-1360

[2] Characterization of a laser-induced plasma by spatially resolved spectroscopy of neutral atom and ion emissions.: Comparison of local and spatially integrated measurements [J].

Aguilera, JA ;

Aragón, C .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2004, 59 (12) :1861-1876

[3]

[Anonymous], 2006, Handbook of Laser-Induced Breakdown Spectroscopy

[4] Influence of the optical depth on spectral line emission from laser-induced plasmas [J].

Aragón, C ;

Bengoechea, J ;

Aguilera, JA .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2001, 56 (06) :619-628

[5] Trace element analysis in water by the laser-induced breakdown spectroscopy technique [J].

Arca, G ;

Ciucci, A ;

Palleschi, V ;

Rastelli, S ;

Tognoni, E .

APPLIED SPECTROSCOPY, 1997, 51 (08) :1102-1105

[6] ROLE OF CRACKS, PORES, AND ABSORBING INCLUSIONS ON LASER-INDUCED DAMAGE THRESHOLD AT SURFACES OF TRANSPARENT DIELECTRICS [J].

BLOEMBERGEN, N .

APPLIED OPTICS, 1973, 12 (04) :661-664

[7] Quantitative analysis of trace metal ions in ice using laser-induced breakdown spectroscopy [J].

Cáceres, JO ;

López, JT ;

Telle, HH ;

Ureña, AG .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2001, 56 (06) :831-838

[8] Experimental investigation and modelling of double pulse laser induced plasma spectroscopy under water [J].

Casavola, A ;

De Giacomo, A ;

Dell'Aglio, M ;

Taccogna, F ;

Colonna, G ;

De Pascale, O ;

Longo, S .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2005, 60 (7-8) :975-985

[9] Laser ignition assisted spark-induced breakdown spectroscopy for the ultra-sensitive detection of trace mercury ions in aqueous solutions [J].

Chen, Yuqi ;

Zhang, Qian ;

Li, Guan ;

Li, Runhua ;

Zhou, Jianying .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2010, 25 (12) :1969-1973

[10] Fast and sensitive trace metal analysis in aqueous solutions by laser-induced breakdown spectroscopy using wood slice substrates [J].

Chen, Zhijiang ;

Li, Hongkun ;

Liu, Ming ;

Li, Runhua .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2008, 63 (01) :64-68

← 1 2 3 4 5 →