Intramolecular σ-Bond Metathesis Between Carbon-Carbon and Silicon-Silicon Bonds

被引：43
|
作者：
Ishida, Naoki [1 ]
Ikemoto, Wataru [1 ]
Murakami, Masahiro [1 ]
机构：
[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Katsura, Kyoto 6158510, Japan
来源：
ORGANIC LETTERS | 2012年 / 14卷 / 12期
关键词：
C-C BOND; RING-ENLARGEMENT OLIGOMERIZATION; SI-SI; CYCLIC DISILANES; PALLADIUM; CLEAVAGE; ACTIVATION; COMPLEXES; CHEMISTRY; HYDROGEN;
D O I：
10.1021/ol301280u
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An intramolecular sigma-bond metathesis between carbon carbon and silicon silicon bonds took place on treatment of a disilane tethered to a cyclobutanone with a palladium(0) catalyst, furnishing a silaindane skeleton as well as an acylsilane functionality at once.
引用
收藏
页码：3230 / 3232
页数：3
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