Crystal Structure and Magnetic Properties of SrNi2-xSb2

被引：4
|
作者：
Gvozdetskyi, Volodymyr [1 ,2 ]
Hlukhyy, Viktor [1 ]
Gladyshevskii, Roman [2 ]
Faessler, Thomas F. [1 ]
机构：
[1] Tech Univ Munich, Dept Chem, D-85747 Garching, Germany
[2] Ivan Franko Natl Univ Lviv, Dept Inorgan Chem, UA-79005 Lvov, Ukraine
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2015年 / 641卷 / 11期
关键词：
Antimonide; Crystal structure; ThCr2Si2; type; Magnetic properties; CABE2GE2; SR; CU;
D O I：
10.1002/zaac.201500518
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The intermetallic phase SrNi2-xSb2 was synthesized by arc melting mixtures of the elements and subsequent annealing under argon, and its structure was investigated by means of both powder and single-crystal X-ray diffraction methods. It crystallizes with the ThCr2Si2 type (tI10, I4/mmm) and has a homogeneity range of x = 0.15(1)-0.28(1), which does not include the exact stoichiometric 1: 2: 2 composition. The crystal structure of the phase SrNi2-xSb2 is built from layers of edge-sharing Ni1-xSb4 tetrahedra, which are separated by Sr atoms along the c direction. Magnetic measurements of SrNi2-xSb2 showed no superconductive transition above 1.8 K.
引用
收藏
页码：1859 / 1862
页数：4
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