A highly selective chemosensor for naked-eye sensing of nanomolar Cu(II) in an aqueous medium

被引:41
|
作者
Qian, Yaao [1 ]
Cao, Li [1 ]
Jia, Chunman [1 ,2 ]
Boamah, Peter Osei [3 ]
Yang, Qiuyun [1 ]
Liu, Chunling [1 ]
Huang, Yan [4 ]
Zhang, Qi [1 ,4 ]
机构
[1] Hainan Univ, Hainan Prov Key Lab Fine Chem, Haikou 570228, Hainan, Peoples R China
[2] Hainan Univ, Natl Minist Educ Trop Resources Utilizat, Key Study Ctr, Haikou 570228, Hainan, Peoples R China
[3] Bolgatanga Polytech, Dept Ecol Agr, Bolgatanga, Ghana
[4] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Jiangsu, Peoples R China
来源
RSC ADVANCES | 2015年 / 5卷 / 95期
基金
中国国家自然科学基金;
关键词
RATIOMETRIC FLUORESCENT-PROBE; COLORIMETRIC CHEMOSENSOR; CU2+ DETECTION; SCHIFF-BASE; ION DETECTION; LIVING CELLS; COPPER IONS; SENSOR; SPECTROMETRY; DERIVATIVES;
D O I
10.1039/c5ra12407g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel highly selective and sensitive colorimetric chemosensor L for the detection of Cu2+ ion with a fast response time was designed and synthesized. Receptor L detected Cu2+ ion by changing its color from colorless to magenta in a semi-aqueous solution. The limit of detection for Cu2+ was calculated to be as low as 28 nM. The possible binding mode of compound L with Cu2+ ion was studied using the Job's method, HRMS, FTIR spectroscopy and H-1 NMR spectroscopy titration. Importantly, test strips containing L were fabricated as a naked-eye indicator for Cu2+ ion in pure water samples.
引用
收藏
页码:77965 / 77972
页数:8
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