Effective growth of boron nitride nanotubes by thermal chemical vapor deposition

被引:200
作者
Lee, Chee Huei [1 ]
Wang, Jiesheng [1 ]
Kayatsha, Vijaya K. [1 ]
Huang, Jian Y. [2 ]
Yap, Yoke Khin [1 ]
机构
[1] Michigan Technol Univ, Dept Phys, Houghton, MI 49931 USA
[2] Sandia Natl Labs, Ctr Integrated Nanotechnol CINT, Albuquerque, NM 87185 USA
基金
美国国家科学基金会;
关键词
D O I
10.1088/0957-4484/19/45/455605
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Effective growth of multiwalled boron nitride nanotubes (BNNTs) has been obtained by thermal chemical vapor deposition (CVD). This is achieved by a growth vapor trapping approach as guided by the theory of nucleation. Our results enable the growth of BNNTs in a conventional horizontal tube furnace within an hour at 1200 degrees C. We found that these BNNTs have an absorption band edge of 5.9 eV, approaching that of single h-BN crystals, which are promising for future nanoscale deep-UV light emitting devices.
引用
收藏
页数:5
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共 26 条
[1]   Electron energy loss spectroscopy measurement of the optical gaps on individual boron nitride single-walled and multiwalled nanotubes -: art. no. 127601 [J].
Arenal, R ;
Stéphan, O ;
Kociak, M ;
Taverna, D ;
Loiseau, A ;
Colliex, C .
PHYSICAL REVIEW LETTERS, 2005, 95 (12)
[2]   GROWTH OF CRYSTAL WHISKERS [J].
BLAKELY, JM ;
JACKSON, KA .
JOURNAL OF CHEMICAL PHYSICS, 1962, 37 (02) :428-&
[3]   STABILITY AND BAND-GAP CONSTANCY OF BORON-NITRIDE NANOTUBES [J].
BLASE, X ;
RUBIO, A ;
LOUIE, SG ;
COHEN, ML .
EUROPHYSICS LETTERS, 1994, 28 (05) :335-340
[4]   A solid-state process for formation of boron nitride nanotubes [J].
Chen, Y ;
Chadderton, LT ;
FitzGerald, J ;
Williams, JS .
APPLIED PHYSICS LETTERS, 1999, 74 (20) :2960-2962
[5]   BORON-NITRIDE NANOTUBES [J].
CHOPRA, NG ;
LUYKEN, RJ ;
CHERREY, K ;
CRESPI, VH ;
COHEN, ML ;
LOUIE, SG ;
ZETTL, A .
SCIENCE, 1995, 269 (5226) :966-967
[6]   Synthesis of boron nitride nanotubes from carbon nanotubes by a substitution reaction [J].
Han, WQ ;
Bando, Y ;
Kurashima, K ;
Sato, T .
APPLIED PHYSICS LETTERS, 1998, 73 (21) :3085-3087
[7]   Optical properties of multiwall boron nitride nanotubes [J].
Jaffrennou, P. ;
Barjon, J. ;
Lauret, J. -S. ;
Maguer, A. ;
Golberg, D. ;
Attal-Tretout, B. ;
Ducastelle, F. ;
Loiseau, A. .
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2007, 244 (11) :4147-4151
[8]   Controlling dissociative adsorption for effective growth of carbon nanotubes [J].
Kayastha, V ;
Yap, YK ;
Dimovski, S ;
Gogotsi, Y .
APPLIED PHYSICS LETTERS, 2004, 85 (15) :3265-3267
[9]   Synthesis of vertically aligned single- and double-walled carbon nanotubes without etching agents [J].
Kayastha, Vijaya Kumar ;
Wu, Shun ;
Moscatello, Jason ;
Yap, Yoke Khin .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (28) :10158-10161
[10]   Deep ultraviolet light-emitting hexagonal boron nitride synthesized at atmospheric pressure [J].
Kubota, Yoichi ;
Watanabe, Kenji ;
Tsuda, Osamu ;
Taniguchi, Takashi .
SCIENCE, 2007, 317 (5840) :932-934