The Tribological Property of a-C:H Coating with Tribolayer by Additive Having Glycerol and Phosphate Oxide Structure

被引:7
作者
Tokoroyama, T. [1 ]
Tanaka, K. [1 ]
Kani, T. [1 ]
Murashima, M. [2 ]
Lee, W-Y [3 ]
Umehara, N. [1 ]
Oshio, T. [4 ]
Yagishita, K. [3 ]
机构
[1] Nagoya Univ, Grad Sch Engn, Dept Micronano Mech Sci & Engn, Chikusa Ku, Furo Cho, Nagoya, Aichi 4648603, Japan
[2] Tohoku Univ, Grad Sch Engn, Dept Mech Syst Engn, Aoba Ku, 6-6-01 Aramaki Aza Aoba, Sendai, Miyagi 9808579, Japan
[3] Korea Photon Technol Inst, Intelligent Opt Module Res Ctr, Gwangju 61007, South Korea
[4] ENEOS Corp, Res & Dev, Chuo Ku, 8 Chidori Cho, Yokohama, Kanagawa 2310815, Japan
关键词
a-C:H; Glycerol and phosphate structure; Additives; GMO; Boundary lubrication; XPS; ToF-SIMS; WEAR PROPERTIES; OIL TEMPERATURE; UV-IRRADIATION; FRICTION; CARBON; DLC; DIAMOND; PERFORMANCE; MODTC; LUBRICATION;
D O I
10.1007/s11249-022-01659-3
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The tribological properties of a-C:H coating sliding against a SUJ2 ball, a SUJ2 roller, and an a-C:H coated roller were investigated under temperatures ranging from 20 to 80 degrees C in PAO with different additives. The additives had a glycerol and hydroxyl functional group in one molecule to enhance additive adsorption for mating with the a-C:H coating disk material and to build a phosphorus oxide tribolayer. Additives with different numbers of hydroxyl groups and primary or secondary-type C6H13O structures were also prepared. The tribolayer derived from each additive was analyzed via EDS, XPS, and ToF-SIMS. XPS depth analysis for the tribolayers revealed that additives were dissociated by friction and suggested C-O bond cleavage occurred.
引用
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页数:17
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