Thermal behavior and thermodynamic properties of berberine hydrochloride

被引：11

作者：

Cheng, X. -X. ^{[1
,2
]}

Lui, Y. ^{[3
]}

Hu, Y. -J. ^{[1
,2
]}

Liu, Y. ^{[1
,2
,6
]}

Li, L. -W. ^{[4
]}

Di, Y. -Y. ^{[4
]}

Xiao, X. -H. ^{[5
]}

机构：

[1] Wuhan Univ, State Key Lab Virol, Wuhan 430072, Peoples R China

[2] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China

[3] Huazhong Univ Sci & Technol, Union Hosp, Dept Pharm, Tongji Med Coll, Wuhan 430022, Peoples R China

[4] Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Peoples R China

[5] Inst Chinese Med PLA, Hosp Peoples Liberat Army, Beijing 100039, Peoples R China

[6] Wuhan Univ, Dept Chem, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2013年 / 114卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Berberine hydrochloride; Adiabatic calorimetry; Combustion calorimetry; TG/DTG; DSC; HEAT-CAPACITY MEASUREMENT; CALORIMETER;

D O I：

10.1007/s10973-009-0288-9

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The low-temperature heat capacities of berberine hydrochloride were measured over the temperature range from 78 to 350 K by an adiabatic calorimeter. The thermodynamic functions H (T) - H (298.15) and S (T) - S (298.15) were derived from the heat capacity data. The results showed that the structure of berberine hydrochloride was stable over the temperature range from 78 to 350 K. The thermal stability of the compound was further tested by DSC and TG measurements. The results were in agreement with those obtained from adiabatic calorimetry experiment. The standard molar enthalpy of formation in the crystalline state of berberine hydrochloride was obtained from the standard molar energies of combustion in oxygen at T = 298.15 K, measured by a rotating-bomb combustion calorimeter.

引用

页码：1401 / 1407

页数：7

共 13 条

[1]

[Anonymous], THERMOMETRY CALORIME

[2] THERMODYNAMIC PROPERTIES OF SYNTHETIC SAPPHIRE (ALPHA-AL2O3), STANDARD REFERENCE MATERIAL 720 AND THE EFFECT OF TEMPERATURE-SCALE DIFFERENCES ON THERMODYNAMIC PROPERTIES [J].

ARCHER, DG .

JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1993, 22 (06) :1441-1453

[3]

*BENZ ACID CAL STA, 1995, CERT AN STAND REF MA

[4]

Cox J. D., 1989, CODATA KEY VALUES TH

[5]

FERARI H, 1969, THERM ANAL, V1, P41

[6] Quaternary protoberberine alkaloids [J].

Grycova, Lenka ;

Dostal, Jiri ;

Marek, Radek .

PHYTOCHEMISTRY, 2007, 68 (02) :150-175

[7] The effect of Berberine on the secondary structure of human serum albumin [J].

Li, Y ;

He, WY ;

Tian, JN ;

Tang, JH ;

Hu, ZD ;

Chen, XG .

JOURNAL OF MOLECULAR STRUCTURE, 2005, 743 (1-3) :79-84

[8] Thermochemical properties of crown ether compounds [J].

Ren, F ;

Yang, XW ;

Gao, SL ;

Ren, DH .

THERMOCHIMICA ACTA, 2001, 375 (1-2) :85-91

[9] A fully automated adiabatic calorimeter for heat capacity measurement between 80 and 400 K [J].

Tan, Z. -C. ;

Shi, Q. ;

Liu, B. -P. ;

Zhang, H. -T. .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2008, 92 (02) :367-374

[10] AN ADIABATIC LOW-TEMPERATURE CALORIMETER FOR HEAT-CAPACITY MEASUREMENT OF SMALL SAMPLES [J].

TAN, ZC ;

SUN, GY ;

SUN, Y ;

YIN, AX ;

WANG, WB ;

YE, JC ;

ZHOU, LX .

JOURNAL OF THERMAL ANALYSIS, 1995, 45 (1-2) :59-67

← 1 2 →