Formation of a mixed valence copper(II)-copper(I) coordination polymer {[Cu(1,2-pn)2(μ3-I)Cu2(μ2-I)3(CH3CN)]•CH3CN}n: in situ reduction of copper(II) at ambient condition

被引：11

作者：

Jana, Subrata ^{[1
]}

Chattopadhyay, Shouvik ^{[1
]}

机构：

[1] Jadavpur Univ, Dept Chem, Inorgan Sect, Kolkata, India

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 66卷 / 22期

关键词：

Copper(II); Copper(I); mu(3)-I; Crystal structure; Coordination polymer; OXIDATIVE DEHYDROGENATION; ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; DICOPPER(I) TRIIODIDE; CU-I; COMPLEXES; LIGAND; CHAIN; CUPROPHILICITY; CLUSTER;

D O I：

10.1080/00958972.2013.854340

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A mixed valence copper(II)-copper(I) coordination polymer has been synthesized starting from a copper(II) salt at ambient condition and characterized by IR and Raman spectra and single crystal X-ray diffraction. The structure of the complex consists of a 1-D infinite chain with repeating unit [Cu(1,2-pn)(2)((3)-I)Cu-2((2)-I)(3)(CH3CN)] and a free CH3CN, where 1,2-pn=1,2-diamino-1-propene. The complex shows a very short copper(I)-copper(I) distance (2.412 angstrom).

引用

页码：3906 / 3914

页数：9

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