A new 3D photoluminescent Cu(I) coordination polymer built from 5-[4-(imidazol-1-yl)phenyl]tetrazolide with 4-connected SrAl2(sra) topology

被引：19
|
作者：
Ma, De-Yun [1 ]
Qin, Liang [1 ]
Lu, Kuan [1 ]
Guo, Hai-Fu [1 ]
Liu, Jian-Qiang [2 ]
机构：
[1] Zhaoqing Univ, Sch Chem & Chem Engn, Zhaoqing 526061, Peoples R China
[2] Guangdong Med Coll, Sch Pharm, Dongguan 523808, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 24卷
关键词：
Copper(I) coordination polymer; Crystal structure; 4-connected SrAl2(sra) topology; Photoluminescence; METAL-ORGANIC FRAMEWORK; SORPTION;
D O I：
10.1016/j.inoche.2012.07.032
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The solvothermal reaction of CuCl2 center dot 2H(2)O with 5-[4-(imidazol-1-yl)phenyl]tetrazolide (HL) generates a new three-dimensional (3D) coordination polymer, [Cu-2(mu(4)-L)(2)](n). In title compound, tetrahedral Cu(I) ions are connected by mu(4)-L bridges into the 3D framework with a 4-connected SrAl2(sra) topology. The result of thermal analysis indicates that title compound is quite stable to heat. Excitation and luminescence data observed at room temperature show that title compound emits bright green fluorescence and possesses moderate fluorescence lifetimes (tau(1) =3.25 mu s, tau(2) = 8.22 mu s at 556 nm). (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：87 / 90
页数：4
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