Regeneration of granular activated carbon loaded with toluene - Comparison of microwave and conductive heating at the same active powers

被引:25
作者
Cherbanski, Robert [1 ]
机构
[1] Warsaw Univ Technol, Chem & Proc Engn Dept, Ul Warynskiego 1, PL-00645 Warsaw, Poland
关键词
Microwaves; Regeneration; Granular activated carbon; Toluene; VOC; VOLATILE ORGANIC-COMPOUNDS; ADSORPTION-DESORPTION; ASSISTED REGENERATION; ADSORBENTS; TECHNOLOGY; ZEOLITES; REMOVAL; VOC;
D O I
10.1016/j.cep.2017.11.008
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
This paper presents a comparison of the microwave and conductive heating regeneration of granular activated carbon loaded with toluene at the same active powers. The purpose of this research was to compare desorption efficiencies and local temperature profiles for the both regeneration methods. Mass balance in the adsorbent bed was carried out by automatic sampling of the outlet gas for the GC analysis instead of weighting the adsorbent bed itself. Five experimental series were performed at constant active power of 12 W and at changing active power in the two-stage program (24 W + 12 W). It was found that the mass profiles of desorbed toluene versus time were practically overlapped for the two regeneration methods when the same active power was applied and the non-insulated vessels were used. Moreover, another comparison demonstrated that proper thermal insulation can be a decisive factor when choosing a particular regeneration method in terms of its economic viability. A comparison of the textural properties of the fresh and regenerated (after 10 successive adsorption/desorption cycles) granular activated carbon (GAC) revealed only slight differences between them. Therefore, it was concluded that the adsorption capacity of GAC is only slightly affected by the both regeneration methods.
引用
收藏
页码:148 / 157
页数:10
相关论文
共 42 条
[1]   Microwave-assisted regeneration of activated carbons loaded with pharmaceuticals [J].
Ania, C. O. ;
Parra, J. B. ;
Menendez, J. A. ;
Pis, J. J. .
WATER RESEARCH, 2007, 41 (15) :3299-3306
[2]   Effect of microwave and conventional regeneration on the microporous and mesoporous network and on the adsorptive capacity of activated carbons [J].
Ania, CO ;
Parra, JB ;
Menéndez, JA ;
Pis, JJ .
MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 85 (1-2) :7-15
[3]   Microwave-induced regeneration of activated carbons polluted with phenol.: A comparison with conventional thermal regeneration [J].
Ania, CO ;
Menéndez, JA ;
Parra, JB ;
Pis, JJ .
CARBON, 2004, 42 (07) :1383-1387
[4]   Physical waves in adsorption technology - an overview [J].
Bathen, D .
SEPARATION AND PURIFICATION TECHNOLOGY, 2003, 33 (02) :163-177
[5]   RECOVERY OF ETHANOL FROM A MOLECULAR-SIEVE BY USING DIELECTRIC HEATING [J].
BURKHOLDER, HR ;
FANSLOW, GE ;
BLUHM, DD .
INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1986, 25 (03) :414-416
[6]   Low temperature regeneration of activated carbons using microwaves: Revising conventional wisdom [J].
Caliskan, E. ;
Bermudez, J. M. ;
Parra, J. B. ;
Menendez, J. A. ;
Mahramanlioglu, M. ;
Ania, C. O. .
JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2012, 102 :134-140
[7]   Microwave technology for treatment of fume hood exhaust [J].
Cha, CY ;
Wallace, S ;
George, AH ;
Rogers, S .
JOURNAL OF ENVIRONMENTAL ENGINEERING-ASCE, 2004, 130 (03) :338-348
[8]   Microwave process for volatile organic compound abatement [J].
Cha, CY ;
Carlisle, CT .
JOURNAL OF THE AIR & WASTE MANAGEMENT ASSOCIATION, 2001, 51 (12) :1628-1641
[9]   Intensification of desorption processes by use of microwaves-An overview of possible applications and industrial perspectives [J].
Cherbanski, R. ;
Molga, E. .
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2009, 48 (01) :48-58
[10]   Modelling of microwave heating of water in a monomode applicator - Influence of operating conditions [J].
Cherbanski, Robert ;
Rudniak, Leszek .
INTERNATIONAL JOURNAL OF THERMAL SCIENCES, 2013, 74 :214-229