Efficient binary organic thiolate/disulfide redox mediators in dye-sensitized solar cells based on a carbon black counter electrode

被引:15
作者
Cho, Woohyung [1 ]
Song, Donghoon [2 ]
Lee, Yong-Gun [1 ]
Chae, Hwaseok [1 ]
Kim, Young Rae [1 ]
Pyun, Yong Bum [1 ]
Nagarajan, S. [1 ]
Sudhagar, P. [1 ]
Kang, Yong Soo [1 ]
机构
[1] Hanyang Univ, Ctr Next Generat Dye Sensitized Solar Cells, WCU Dept Energy Engn, Seoul 133791, South Korea
[2] Hanyang Univ, Dept Chem Engn, Seoul 133791, South Korea
基金
新加坡国家研究基金会;
关键词
LOW-COST; COUPLES;
D O I
10.1039/c2ta00719c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
New thiolate/disulfide redox couples (M-/M-2) were introduced and also combined with T-/T-2, resulting in more efficient binary redox couples. The binary redox couples, in particular M-/T-2, yielded a high energy conversion efficiency and reasonably stable performance with the carbon black counter electrode for dye-sensitized solar cells.
引用
收藏
页码:233 / 236
页数:4
相关论文
共 24 条
[1]   Characteristics of the Iodide/Triiodide Redox Mediator in Dye-Sensitized Solar Cells [J].
Boschloo, Gerrit ;
Hagfeldt, Anders .
ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (11) :1819-1826
[2]   Influence of the counter electrode on the photovoltaic performance of dye-sensitized solar cells using a disulfide/thiolate redox electrolyte [J].
Burschka, Julian ;
Brault, Vincent ;
Ahmad, Shahzada ;
Breau, Livain ;
Nazeeruddin, Mohammad K. ;
Marsan, Benoit ;
Zakeeruddin, Shaik M. ;
Graetzel, Michael .
ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (03) :6089-6097
[3]   Efficient non-corrosive electron-transfer mediator mixtures for dye-sensitized solar cells [J].
Cazzanti, Silvia ;
Caramori, Stefano ;
Argazzi, Roberto ;
Elliott, C. Michael ;
Bignozzi, Carlo Alberto .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (31) :9996-9997
[4]   Highly Efficient Light-Harvesting Ruthenium Sensitizer for Thin-Film Dye-Sensitized Solar Cells [J].
Chen, Chia-Yuan ;
Wang, Mingkui ;
Li, Jheng-Ying ;
Pootrakulchote, Nuttapol ;
Alibabaei, Leila ;
Ngoc-le, Cevey-ha ;
Decoppet, Jean-David ;
Tsai, Jia-Hung ;
Graetzel, Carole ;
Wu, Chun-Guey ;
Zakeeruddin, Shaik M. ;
Graetzel, Michael .
ACS NANO, 2009, 3 (10) :3103-3109
[5]  
Daeneke T, 2011, NAT CHEM, V3, P211, DOI [10.1038/nchem.966, 10.1038/NCHEM.966]
[6]   Dynamic response of dye-sensitized nanocrystalline solar cells: Characterization by intensity-modulated photocurrent spectroscopy [J].
Dloczik, L ;
Ileperuma, O ;
Lauermann, I ;
Peter, LM ;
Ponomarev, EA ;
Redmond, G ;
Shaw, NJ ;
Uhlendorf, I .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (49) :10281-10289
[7]   INDUCTION COILS COAXIAL WITH AN ARBITRARY NUMBER OF CYLINDRICAL CONDUCTORS [J].
DODD, CV ;
CHENG, CC ;
DEEDS, WE .
JOURNAL OF APPLIED PHYSICS, 1974, 45 (02) :638-647
[8]   Design of Organic Dyes and Cobalt Polypyridine Redox Mediators for High-Efficiency Dye-Sensitized Solar Cells [J].
Feldt, Sandra M. ;
Gibson, Elizabeth A. ;
Gabrielsson, Erik ;
Sun, Licheng ;
Boschloo, Gerrit ;
Hagfeldt, Anders .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (46) :16714-16724
[9]   High-efficiency organic-dye-sensitized solar cells controlled by nanocrystalline-TiO2 electrode thickness [J].
Ito, Seigo ;
Zakeeruddin, Shaik M. ;
Humphry-Baker, Robin ;
Liska, Paul ;
Charvet, Raphael ;
Comte, Pascal ;
Nazeeruddin, Mmad K. ;
Pechy, Peter ;
Takata, Masakazu ;
Miura, Hidetoshi ;
Uchida, Satoshi ;
Graetzel, Michael .
ADVANCED MATERIALS, 2006, 18 (09) :1202-+
[10]   Ni(III)/(IV) Bis(dicarbollide) as a Fast, Noncorrosive Redox Shuttle for Dye-Sensitized Solar Cells [J].
Li, Tina C. ;
Spokoyny, Alexander M. ;
She, Chunxing ;
Farha, Omar K. ;
Mirkin, Chad A. ;
Marks, Tobin J. ;
Hupp, Joseph T. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (13) :4580-+