Crystal structure, superoxide dismutase activity and electrochemical property of complex [Cu(dtne)] • (ClO4)2 • CH3CH2OH

被引：6

作者：

Li, Qing-Xiang ^{[1
]}

Wang, Xiu-Feng ^{[1
]}

Cai, Li ^{[1
]}

Li, Qiao ^{[1
]}

Meng, Xiang-Gao ^{[2
]}

Xuan, Ai-Guo ^{[1
]}

Huang, Shao-Yun ^{[1
]}

Ai, Jun ^{[1
]}

机构：

[1] Wuhan Inst Technol, Hubei Key Lab Novel Chem Reactor & Green Chem Tec, Wuhan 430073, Peoples R China

[2] Huazhong Normal Univ, Coll Chem, Wuhan 430079, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2009年 / 12卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Crystal structure; Copper (II) complex; Superoxide dismutase mimic; Electrochemical property; MODEL; 1,4,7-TRIAZACYCLONONANE; EQUILIBRIUM; HEMERYTHRIN; LIGAND;

D O I：

10.1016/j.inoche.2008.11.028

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new copper (II) complex [Cu(dtne)] center dot (ClO4)(2) center dot CH3CH2OH, where dtne is 1,2-bis(1,4,7-triaza-1-cyclononyl)ethane, was prepared and characterized by X-ray crystallography. The result shows that in the complex the copper (II) adopts an octahedral coordination geometry. The cyclic voltammetry of the complex recorded in aqueous solution indicates a reversible one-electron redox reaction. The activity of dismutation of superoxide (center dot O-2(-)) of the complex in the riboflavin-methionine-nitro blue tetrazolium assay has been researched. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：145 / 147

页数：3

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