Multidentate aminophenol ligands prepared with Mannich condensations

被引：54

作者：

Higham, Christine S.

Dowling, Daniel P.

Shaw, Janet L.

Cetin, Anil

Ziegler, Christopher J.

Farrell, Joshua R. ^{[1
]}

机构：

[1] Coll Holy Cross, Dept Chem, Worcester, MA 01610 USA

[2] Univ Akron, Dept Chem, Akron, OH 44325 USA

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 26期

基金：

美国国家科学基金会;

关键词：

Mannich condensation; Zn(II); benzoxazine;

D O I：

10.1016/j.tetlet.2006.04.077

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Mannich condensations were used to prepare a series of multidentate aminophenol compounds from ethylenediamine. various amounts of paraformaldehyde and 2,4-disubstituted phenols. One of these diaminotetraphenol compounds was reacted with Zn(OAc)(2)(.)2H(2)O and the resulting solid state structure of the pentacoordinated Zn(II) compound was determined by single crystal X-ray diffraction analysis. (c) 2006 Elsevier Ltd. All rights reserved.

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页码：4419 / 4423

页数：5

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