Reduced graphene oxide doped predominantly with CF2 groups as a superior anode material for long-life lithium-ion batteries

被引：43
作者：
An, Haoran [1 ]
Li, Yu [1 ,2 ,3 ]
Feng, Yiyu [1 ,2 ,3 ]
Cao, Yu [1 ]
Cao, Chen [1 ]
Long, Peng [1 ]
Li, Shuangwen [1 ]
Feng, Wei [1 ,2 ,3 ,4 ]
机构：
[1] Tianjin Univ, Sch Mat Sci & Engn, Tianjin 300072, Peoples R China
[2] Minist Educ, Key Lab Adv Ceram & Machining Technol, Tianjin 300072, Peoples R China
[3] Tianjin Key Lab Composite & Funct Mat, Tianjin 300072, Peoples R China
[4] Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300072, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 22期
基金：
中国国家自然科学基金;
关键词：
HIGH-PERFORMANCE ANODE; FLUORINATED GRAPHENE; ELECTRODE MATERIALS; ENERGY-STORAGE; NITROGEN; CHALLENGES; HYBRID; SHEETS;
D O I：
10.1039/c7cc09516c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A fluorine-doped reduced graphene oxide (F-rGO), predominantly in the form of CF2 groups, was synthesized using the reduced-graphene-oxide precursor devoid of residual hydroxyl and carboxyl groups through a solvothermal process. The vacancies and defects accompanying the formation of the highly stable and electrochemically inert CF2 groups contribute to the excellent cycling stability of F-rGO, when it is applied as the anode material in a lithium-ion battery.
引用
收藏
页码：2727 / 2730
页数：4
相关论文
共 35 条
[1]   Nitrogen and Sulfur Codoped Graphene: Multifunctional Electrode Materials for High-Performance Li-Ion Batteries and Oxygen Reduction Reaction [J].
Ai, Wei ;
Luo, Zhimin ;
Jiang, Jian ;
Zhu, Jianhui ;
Du, Zhuzhu ;
Fan, Zhanxi ;
Xie, Linghai ;
Zhang, Hua ;
Huang, Wei ;
Yu, Ting .
ADVANCED MATERIALS, 2014, 26 (35) :6186-+
[2]   Free-standing fluorine and nitrogen co-doped graphene paper as a high-performance electrode for flexible sodium-ion batteries [J].
An, Haoran ;
Li, Yu ;
Gao, Yi ;
Cao, Chen ;
Han, Junkai ;
Feng, Yiyu ;
Feng, Wei .
CARBON, 2017, 116 :338-346
[3]   Hydrothermal preparation of fluorinated graphene hydrogel for high-performance supercapacitors [J].
An, Haoran ;
Li, Yu ;
Long, Peng ;
Gao, Yi ;
Qin, Chengqun ;
Cao, Chen ;
Feng, Yiyu ;
Feng, Wei .
JOURNAL OF POWER SOURCES, 2016, 312 :146-155
[4]   Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage [J].
Bonaccorso, Francesco ;
Colombo, Luigi ;
Yu, Guihua ;
Stoller, Meryl ;
Tozzini, Valentina ;
Ferrari, Andrea C. ;
Ruoff, Rodney S. ;
Pellegrini, Vittorio .
SCIENCE, 2015, 347 (6217)
[5]   Hydrothermal synthesis of macroscopic nitrogen-doped graphene hydrogels for ultrafast supercapacitor [J].
Chen, Ping ;
Yang, Jing-Jing ;
Li, Shan-Shan ;
Wang, Zheng ;
Xiao, Tian-Yuan ;
Qian, Yu-Hong ;
Yu, Shu-Hong .
NANO ENERGY, 2013, 2 (02) :249-256
[6]   Hollow Carbon-Nanotube/Carbon-Nanofiber Hybrid Anodes for Li-Ion Batteries [J].
Chen, Yuming ;
Li, Xiaoyan ;
Park, Kyusung ;
Song, Jie ;
Hong, Jianhe ;
Zhou, Limin ;
Mai, Yiu-Wing ;
Huang, Haitao ;
Goodenough, John B. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (44) :16280-16283
[7]   Challenges in the development of advanced Li-ion batteries: a review [J].
Etacheri, Vinodkumar ;
Marom, Rotem ;
Elazari, Ran ;
Salitra, Gregory ;
Aurbach, Doron .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) :3243-3262
[8]   Two-Dimensional Fluorinated Graphene: Synthesis, Structures, Properties and Applications [J].
Feng, Wei ;
Long, Peng ;
Feng, Yiyu ;
Li, Yu .
ADVANCED SCIENCE, 2016, 3 (07)
[9]   A Chemically Coupled Antimony/Multilayer Graphene Hybrid as a High-Performance Anode for Sodium-Ion Batteries [J].
Hu, Lingyun ;
Zhu, Xiaoshu ;
Du, Yichen ;
Li, Yafei ;
Zhou, Xiaosi ;
Bao, Jianchun .
CHEMISTRY OF MATERIALS, 2015, 27 (23) :8138-8145
[10]   Nitrogen and fluorine co-doped graphene as a high-performance anode material for lithium-ion batteries [J].
Huang, Shizheng ;
Li, Yu ;
Feng, Yiyu ;
An, Haoran ;
Long, Peng ;
Qin, Chengqun ;
Feng, Wei .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (46) :23095-23105
1234