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Density, Speed of Sound, and Viscosity of Diethylene Glycol Monoethyl Ether plus N,N-Dimethylformamide (Ethanol, Water) at T=288.15-318.15 K
被引:28
作者:
Mirheydari, Seyyedeh Narjes
[1
]
Barzegar-Jalali, Mohammad
[2
,3
]
Golmohamadi, Behrang
[4
]
Shekaari, Hemayat
[4
]
Martinez, Fleming
[5
]
Jouyban, Abolghasem
[3
,6
,7
]
机构:
[1] Tabriz Univ Med Sci, Drug Appl Res Ctr, Tabriz, Iran
[2] Tabriz Univ Med Sci, Res Ctr Pharmaceut Nanotechnol, Tabriz, Iran
[3] Tabriz Univ Med Sci, Fac Pharm, Tabriz, Iran
[4] Univ Tabriz, Dept Phys Chem, Fac Chem, Tabriz, Iran
[5] Univ Nacl Colombia, Fac Ciencias, Dept Farm, Grp Invest Farmaceuticofisicoquim, Cra 30 45-03, Bogota, DC, Colombia
[6] Tabriz Univ Med Sci, Pharmaceut Anal Res Ctr, Tabriz, Iran
[7] Tabriz Univ Med Sci, Kimia Idea Pardaz Azarbayjan KIPA Sci Based Co, Tabriz, Iran
关键词:
EXCESS MOLAR VOLUMES;
LIQUID API-IL;
BINARY-MIXTURES;
IONIC LIQUID;
AQUEOUS-SOLUTIONS;
HEAT-CAPACITIES;
ISOTHERMAL COMPRESSIBILITIES;
PHYSICOCHEMICAL PROPERTIES;
THERMODYNAMIC PROPERTIES;
ATMOSPHERIC-PRESSURE;
D O I:
10.1021/acs.jced.8b01012
中图分类号:
O414.1 [热力学];
学科分类号:
摘要:
The density (rho), speed of sound (u), and viscosity (eta) of the binary mixtures of (diethylene glycol monoethyl ether (carbitol) and water, ethanol, N,N-dimethylformamide) have been measured in full concentration range at T = 288.15, 298.15, 308.15, and 318.15 K and p = 0.0868 MPa. Using the experimental data, the molar volume (V-m), excess molar volume (V-m(E)), isentropic compressibility (K-s), excess molar isentropic compressibility (k(s,m)(E)), and viscosity deviation (Delta(eta))O were calculated. The most negative values of V-m(E) and K-s,m(E) and positive values of Delta(eta) obtained for the carbitol + water mixture are indicative of the strong interactions between different components relative to two other systems. The values of rho, V-m, and K-s for the studied mixtures were correlated using the Jouyban-Acree model with high accuracy. Furthermore, the obtained values of V-m(E), k(s,m)(E), and Delta(eta) were described by the Redlich-Kister equation and reasonable standard deviations were obtained.
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页码:1425 / 1436
页数:12
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