Benzoannelated valence isomers of homoannulenes .4. Flow vacuum pyrolysis of 1,2,3,3a,8,8a-hexahydro-2,3,8-methenocyclopentindene

被引：15

作者：

Banciu, MD ^{[1
]}

Olteanu, E ^{[1
]}

Draghici, C ^{[1
]}

Petride, A ^{[1
]}

Danila, M ^{[1
]}

机构：

[1] ROMANIAN ACAD,CD NENITZESCU INST ORGA CHEM,BUCHAREST 71141,ROMANIA

来源：

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 1996年 / 37卷 / 02期

关键词：

benzo(C9H10)hydrocarbons; flow vacuum pyrolysis; pyrolysis; thermal isomerization; valence isomers of homoannulenes;

D O I：

10.1016/0165-2370(96)00940-0

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Pyrolysis of 1,2,3,3a,8,8a-hexahydro-2,3,8-methenocyclopentindene in a flow system at 1.33 mbar, in an argon atmosphere and at temperatures between 500 and 750 degrees C was studied by GC/MS. The first pyrolysis product, 1,6-dihydro-1,6-methanobenzo[d]cyclooctene (a new compound), was converted at elevated temperatures into mainly alpha- and beta-allylnaphthalenes and fluorene. A reaction mechanism including radical and concerted steps is suggested.

引用

页码：151 / 160

页数：10

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