Time-temperature and time-density superposition in the simulation of rheological properties of polymers

被引：7
|
作者：
Rouault, Y [1 ]
Kremer, K [1 ]
机构：
[1] Max Planck Inst Polymerforsch, D-55021 Mainz, Germany
来源：
JOURNAL OF CHEMICAL PHYSICS | 1999年 / 111卷 / 07期
关键词：
D O I：
10.1063/1.479608
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Applying a periodical elongational strain in a computer simulation of polymer melts and networks, we are able for the first time to employ a time-temperature and time-density superposition in a numerical experiment for the study of the dynamic moduli. The simulation results can be analyzed and understood within the semiempirical free volume concept. (C) 1999 American Institute of Physics. [S0021-9606(99)51129-X].
引用
收藏
页码：3288 / 3293
页数：6
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