Optimization of a PEM fuel cell operating conditions: Obtaining the maximum performance polarization curve

被引:73
作者
Antonio Salva, J. [1 ]
Iranzo, Alfredo [1 ]
Rosa, Felipe [2 ]
Tapia, Elvira [1 ]
Lopez, Eduardo [3 ]
Isorna, Fernando [3 ]
机构
[1] Univ Seville, Sch Engn, Andalusian Assoc Res & Ind Cooperat, AICIA, Camino Descubrimientos S-N, Seville 41092, Spain
[2] Univ Seville, Sch Engn, Energy Engn Dept, Thermal Engn Grp, Camino Descubrimientos S-N, Seville 41092, Spain
[3] Natl Inst Aerosp Technol, INTA, Ctra San Juan del Puerto Matalascanas,Km 33, Mazagon 21130, Huelva, Spain
关键词
Single PEM fuel cell; Analytical validated model; Optimization; Operating conditions; Polarization curve; BIPOLAR PLATES; MODEL;
D O I
10.1016/j.ijhydene.2016.03.136
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This work presents the operating conditions optimization of a 50 cm(2) PEM fuel cell using a one dimensional analytical model previously validated against experimental data for a comprehensive set of different operating conditions of cell temperature, pressure, reactants relative humidity and cathode stoichiometry. The analytical model is used to predict the operating conditions that provide the maximum (and the minimum) power output of the given PEM fuel cell for every value of current intensity. Thus, a maximum performance polarization curve is developed where the operating conditions are not fixed for every current intensity, but modified in order to provide the maximum possible power output for every value of current intensity. The obtained operating conditions have been tested in the real cell showing a good agreement between experimental and modeling results where the maximum error is below 2% for the case of maximum power and 3% for the case of minimum power. The comparison shows that the power output using the operating conditions for the curve of maximum power is about 100% higher than using the curve of minimum power. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:19713 / 19723
页数:11
相关论文
共 20 条
[1]   Validation of cell voltage and water content in a PEM (polymer electrolyte membrane) fuel cell model using neutron imaging for different operating conditions [J].
Antonio Salva, J. ;
Iranzo, Alfredo ;
Rosa, Felipe ;
Tapia, Elvira .
ENERGY, 2016, 101 :100-112
[2]   Technical cost analysis for PEM fuel cells [J].
Bar-On, I ;
Kirchain, R ;
Roth, R .
JOURNAL OF POWER SOURCES, 2002, 109 (01) :71-75
[3]   Experimental measurement of effective diffusion coefficient of gas diffusion layer/microporous layer in PEM fuel cells [J].
Chan, Carl ;
Zamel, Nada ;
Li, Xianguo ;
Shen, Jun .
ELECTROCHIMICA ACTA, 2012, 65 :13-21
[4]  
Frano B., 2005, PEM FUEL CELLS THEOR
[5]   Numerical model for the performance prediction of a PEM fuel cell. Model results and experimental validation [J].
Iranzo, Alfredo ;
Munoz, Miguel ;
Rosa, Felipe ;
Pino, Javier .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (20) :11533-11550
[6]   Cost-benefit analysis of commercial bipolar plates for PEMFC's [J].
Jayakumar, K. ;
Pandiyan, S. ;
Rajalakshmi, N. ;
Dhathathreyan, K. S. .
JOURNAL OF POWER SOURCES, 2006, 161 (01) :454-459
[7]  
Kabza DA, 2015, FUEL CELL FORMULARY
[8]   Model development and optimization of operating conditions to maximize PEMFC performance by response surface methodology [J].
Kanani, Homayoon ;
Shams, Mehrzad ;
Hasheminasab, Mohammadreza ;
Bozorgnezhad, Ali .
ENERGY CONVERSION AND MANAGEMENT, 2015, 93 :9-22
[9]   Review of bipolar plates in PEM fuel cells: Flow-field designs [J].
Li, XG ;
Sabir, M .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2005, 30 (04) :359-371
[10]  
Makkus R.C., 2000, FUEL CELLS B, V3, P5