TEMPO-Mediated Oxidation of Primary Alcohols to Aldehydes under Visible Light and Air

被引：31
作者：
Liu, Dongwang [1 ]
Zhou, Hongxia [1 ]
Gu, Xiangyong [1 ]
Shen, Xiaoqin [1 ]
Li, Pixu [1 ]
机构：
[1] Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Jiangsu, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2014年 / 32卷 / 02期
基金：
中国国家自然科学基金;
关键词：
alcohol; aldehyde; photooxidation; TEMPO; molecular oxygen; CATALYZED AEROBIC OXIDATION; TRANSITION-METAL-FREE; HIGHLY EFFICIENT; MOLECULAR-OXYGEN; SELECTIVE OXIDATION; DIMETHYL-SULFOXIDE; KETONES; PHOTOOXIDATION; COMBINATION; NITRATE;
D O I：
10.1002/cjoc.201300541
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A homogeneous visible light photoredox TEMPO-mediated selective oxidation of primary alcohols to the corresponding carbonyl compounds was developed using molecular oxygen from air as the terminal oxidant. Ru(bpy)(3)(PF6)(2) (bpy: bipyridyl) and Ir(dtb-bpy)(ppy)(2)(PF6) (dtb-bpy: 4,4-di-tert-butyl-2,2-bipyridyl; ppy: 2-phenylpyridine) were used as the sensitizers.
引用
收藏
页码：117 / 122
页数：6
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