Application of polyethyleneglycol (PEG) functionalized ionic liquids for the rhodium-catalyzed hydrosilylation reaction of alkenes

被引：13
作者：
Bai, Ying [1 ]
Zhang, Fengxiang [1 ]
Li, Jiayun [1 ]
Xu, Yisong [1 ]
Peng, Jiajian [1 ]
Xiao, Wenjun [1 ]
机构：
[1] Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 311121, Zhejiang, Peoples R China
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2015年 / 794卷
基金：
中国国家自然科学基金;
关键词：
Hydrosilylation; Rh(PPh3)(3)Cl; PEG functionalized ionic liquids; MOLTEN-SALT; COMPLEXES; LIGANDS;
D O I：
10.1016/j.jorganchem.2015.06.024
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Rh(PPh3)(3)Cl-polyethyleneglycol (PEG) functionalized ionic liquids with various anions were used as a catalytic system for the hydrosilylation reaction of alkenes. The influence of the anion of the ionic liquid has been investigated. It was found that the anion has an impact on the catalytic activity and selectivity. [PEG(400)DIL][PF6]-[Rh(PPh3)(3)Cl] shows an improved catalytic performance towards the hydrosilylation reaction of alkenes. The scope of alkenes and recycling of the catalytic system have been investigated. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：65 / 69
页数：5
相关论文
共 20 条
[1]   Recent advances in oxidation catalysis using ionic liquids as solvents [J].
Betz, Daniel ;
Altmann, Philipp ;
Cokoja, Mirza ;
Herrmann, Wolfgang A. ;
Kuehn, Fritz E. .
COORDINATION CHEMISTRY REVIEWS, 2011, 255 (13-14) :1518-1540
[2]   Enantioselective catalysis.: Part 148:: Carbohydrate-derived oxime ethers stable towards hydrolysis-syntheses of ligands and complexes and a study of their catalytic properties [J].
Brunner, H ;
Schönherr, M ;
Zabel, M .
TETRAHEDRON-ASYMMETRY, 2003, 14 (09) :1115-1122
[3]   Ionic liquid (molten salt) phase organometallic catalysis [J].
Dupont, J ;
de Souza, RF ;
Suarez, PAZ .
CHEMICAL REVIEWS, 2002, 102 (10) :3667-3691
[4]   MCM-41-Supported Bidentate Phosphine Rhodium Complex: An Efficient and Recyclable Heterogeneous Catalyst for the Hydrosilylation of Olefins [J].
Hu Ronghua ;
Hao Wenyan ;
Cai Mingzhong .
CHINESE JOURNAL OF CHEMISTRY, 2011, 29 (08) :1629-1634
[5]   Rhodium-Catalyzed Alkene Hydrosilylation via a Hydride Shuttle Process by Diene Ligands: Dramatic Enhancement of Regio- and Diastereoselectivity [J].
Hua, Yuanda ;
Nguyen, Hiep H. ;
Trog, Gabriela ;
Berlin, Adam S. ;
Jeon, Junha .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2014, 2014 (27) :5890-5895
[6]   P/S ligands derived from carbohydrates in Rh-catalyzed hydrosilylation of ketones [J].
Khiar, Noureddine ;
Pernia Leal, Manuel ;
Navas, Raquel ;
Francisco Moya, Juan ;
Garcia Perez, Maria Victoria ;
Fernandez, Inmaculada .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2012, 10 (02) :355-360
[7]   Hydrosilylation reactions catalyzed by rhodium complexes with phosphine ligands functionalized with imidazolium salts [J].
Li, Jiayun ;
Peng, Jiajian ;
Wang, Diliang ;
Bai, Ying ;
Jiang, Jianxiong ;
Lai, Guoqiao .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (01) :263-268
[8]   Synthesis of rhodium N-heterocyclic carbene complexes and their catalytic activity in the hydrosilylation of alkenes in ionic liquid medium [J].
Li, Jiayun ;
Peng, Jiajian ;
Bai, Ying ;
Lai, Guoqiao ;
Li, Xiaonian .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (10) :2116-2121
[9]   Hydrosilylation catalysed by a rhodium complex in a supercritical CO2/ionic liquid system [J].
Li, Jiayun ;
Peng, Jiajian ;
Zhang, Guodong ;
Bai, Ying ;
Lai, Guoqiao ;
Li, Xiaonian .
NEW JOURNAL OF CHEMISTRY, 2010, 34 (07) :1330-1334
[10]   Phosphines with 2-imidazolium ligands enhance the catalytic activity and selectivity of rhodium complexes for hydrosilylation reactions [J].
Li, Jiayun ;
Peng, Jiajian ;
Bai, Ying ;
Zhang, Guodong ;
Lai, Guoqiao ;
Li, Xiaonian .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2010, 695 (03) :431-436
12