An efficient synthesis of versatile terpyridine analogues for cyclometallated luminescent cyclodextrins

被引:24
作者
Chavarot, M [1 ]
Pikramenou, Z [1 ]
机构
[1] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
关键词
Negishi's cross-coupling; luminescent cyclodextrins; ruthenium complexes;
D O I
10.1016/S0040-4039(99)01386-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An efficient synthetic method for preparing functionalised terpyridyl analogues based on Negishi's zinc coupling is developed. These ligands form cyclometallated complexes; attaching them to cyclodextrins allows preparation of luminescent cyclometallated ruthenium cyclodextrins for the assembly of photoactive units via non-covalent interactions, (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:6865 / 6868
页数:4
相关论文
共 11 条
[1]   Energy transfer in rigid Ru(II)/Os(II) dinuclear complexes with biscyclometalating bridging ligands containing a variable number of phenylene units [J].
Barigelletti, F ;
Flamigni, L ;
Guardigli, M ;
Juris, A ;
Beley, M ;
ChodorowskiKimmes, S ;
Collin, JP ;
Sauvage, JP .
INORGANIC CHEMISTRY, 1996, 35 (01) :136-142
[2]   3,3',5,5'-TETRAPYRIDYLBIPHENYL - A BISCYCLOMETALATING BRIDGING LIGAND WITH A HIGH COUPLING ABILITY IN RU(III),RU(II) MIXED-VALENCE SYSTEMS [J].
BELEY, M ;
COLLIN, JP ;
LOUIS, R ;
METZ, B ;
SAUVAGE, JP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (22) :8521-8522
[3]   SYNTHESIS OF BIS-CYCLOMETALLATING N-C-N HEXADENTATE LIGANDS VIA C-C AROMATIC COUPLINGS AND THEIR DINUCLEAR RUTHENIUM(II) COMPLEXES [J].
BELEY, M ;
CHODOROWSKI, S ;
COLLIN, JP ;
SAUVAGE, JP .
TETRAHEDRON LETTERS, 1993, 34 (18) :2933-2936
[4]   A convenient synthesis of mono-6-hydroxy permethylated beta-cyclodextrin via tert-butyldimethylsilylation [J].
Chen, Z ;
Bradshaw, JS ;
Lee, ML .
TETRAHEDRON LETTERS, 1996, 37 (38) :6831-6834
[5]   CYCLOMETALLATION REACTIONS OF 6-PHENYL-2,2'-BIPYRIDINE - A POTENTIAL C,N,N-DONOR ANALOG OF 2,2'-6',2''-TERPYRIDINE - CRYSTAL AND MOLECULAR-STRUCTURE OF DICHLOROBIS(6-PHENYL-2,2'-BIPYRIDINE)RUTHENIUM(II) [J].
CONSTABLE, EC ;
HENNEY, RPG ;
LEESE, TA ;
TOCHER, DA .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (02) :443-449
[6]   SOLVENT EFFECTS IN THE REACTIONS OF 6-PHENYL-2,2'-BIPYRIDINE WITH RUTHENIUM(II) [J].
CONSTABLE, EC ;
HANNON, MJ .
INORGANICA CHIMICA ACTA, 1993, 211 (01) :101-110
[7]   COMPLEXES OF THE RUTHENIUM(II)-2,2'/6',2''-TERPYRIDINE FAMILY - EFFECT OF ELECTRON-ACCEPTING AND ELECTRON-DONATING SUBSTITUENTS ON THE PHOTOPHYSICAL AND ELECTROCHEMICAL PROPERTIES [J].
MAESTRI, M ;
ARMAROLI, N ;
BALZANI, V ;
CONSTABLE, EC ;
THOMPSON, AMWC .
INORGANIC CHEMISTRY, 1995, 34 (10) :2759-2767
[8]   A supramolecular chemosensor for aromatic hydrocarbons [J].
Mortellaro, MA ;
Nocera, DG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (31) :7414-7415
[9]  
NEGISHI E, 1988, ORG SYNTH, V66, P67
[10]  
Rudzinski CM, 1998, COORDIN CHEM REV, V171, P115