Weak Te,Te Interactions through the Looking Glass of NMR SpinSpin Coupling

被引：32

作者：

Buehl, Michael ^{[1
]}

Knight, Fergus R. ^{[1
]}

Kristkova, Anezka ^{[2
]}

Ondik, Irina Malkin ^{[3
]}

Malkina, Olga L. ^{[2
]}

Randall, Rebecca A. M. ^{[1
]}

Slawin, Alexandra M. Z. ^{[1
]}

Woollins, J. Derek ^{[1
]}

机构：

[1] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[2] Slovak Acad Sci, Inst Inorgan Chem, Bratislava 84536, Slovakia

[3] Comenius Univ, Fac Math Phys & Informat, Bratislava 84248, Slovakia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 09期

关键词：

naphthalenes; quantum-chemical computation; tellurium; through-bond interactions; through-space interactions; SOLID-STATE NMR; DISTANCE DEPENDENCE; BOND; NAPHTHALENE; PARAMETERS; CONSTANTS; PAIRS;

D O I：

10.1002/anie.201205998

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Across the bay: J(125Te,125Te) spin-spin coupling is a highly sensitive probe into the electronic and geometric structure of 1,8-peri-substituted naphthalene tellurium derivatives. The coupling is related to the onset of multicenter bonding in these systems. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2495 / 2498

页数：4

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