Solvents for sustainable chemical processes

被引：187

作者：

Pollet, Pamela ^{[1
,2
]}

Davey, Evan A. ^{[1
]}

Urena-Benavides, Esteban E. ^{[3
]}

Eckert, Charles A. ^{[1
,2
,3
]}

Liotta, Charles L. ^{[1
,2
,3
]}

机构：

[1] Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA

[2] Georgia Inst Technol, Specialty Separat Ctr, Atlanta, GA 30332 USA

[3] Georgia Inst Technol, Sch Chem & Biomol Engn, Atlanta, GA 30332 USA

来源：

GREEN CHEMISTRY | 2014年 / 16卷 / 03期

关键词：

NEAR-CRITICAL WATER; SUPERCRITICAL-CARBON-DIOXIDE; HIGH-TEMPERATURE WATER; SOLVATOCHROMIC COMPARISON METHOD; PRESSURE PHASE-EQUILIBRIA; REVERSIBLE IONIC LIQUIDS; GAS-EXPANDED LIQUIDS; IN-SITU; GREEN CHEMISTRY; CONTINUOUS PHOTOOXIDATION;

D O I：

10.1039/c3gc42302f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The properties and some key applications of solvents such as (1) supercritical fluids (SCFs), (2) gas-expanded liquids (GXLs) and organic-aqueous tunable solvents (OATS), (3) water at elevated temperature (WET), and (4) switchable solvents like reversible ionic liquids (RevILs) are discussed in this review. Each system offers a unique set of properties to enable alternative strategies for varied applications. These applications range from chemical transformations, product separation, catalyst recycling, nanomaterial processing, and CO2 capture. For each application, however, the common thrust is to enable greener and sustainable solutions for chemical processes.

引用

页码：1034 / 1055

页数：22

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