Synthesis, crystal structure, and photoluminescence of a lithium isothiocyanate compound with 18-crown-6

被引：3

作者：

Fu, Shan ^{[1
]}

Fu, Bo ^{[1
]}

Zhao, Zhen ^{[1
]}

Liu, Xi ^{[1
]}

机构：

[1] Chongqing Normal Univ, Coll Chem, Chongqing Key Lab Inorgan Funct Mat, Chongqing 401331, Peoples R China

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2018年 / 73卷 / 02期

基金：

中国国家自然科学基金;

关键词：

crown ether; crystal structure; isothiocyanate; lithium; photoluminescence; CYCLIC POLYETHERS; METAL-SALTS; COMPLEXES; 1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE; LUMINESCENCE; DIHYDRATE;

D O I：

10.1515/znb-2017-0171

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The investigation of the supramolecular interactions between the lithium isothiocyanate salt and 18-crown-6 (18C-6) in commercial tetrahydrofuran leads to the formation of a lithium compound, LiNCS(H2O) (18C-6) (1). In the crystal structure the asymmetric unit contains two similar LiNCS(H2O)(18C-6) molecules. Solid-state photoluminescence experiments have shown that compound 1 emits violet luminescence, and its possible emission mechanism was investigated in detail based on theoretical calculations.

引用

页码：85 / 89

页数：5

共 15 条

[1] CHANG TL, 1987, REV CHIM MINER, V24, P382
[2] Crystal structure of the complex of 1,4,7,10,13,16-hexaoxacyclooctadecane with lithium picrate dihydrate
Dalley, NK
Lamb, JD
Nazarenko, AY
[J]. SUPRAMOLECULAR CHEMISTRY, 1997, 8 (04) : 345 - 350
[3] METAL-BONDING VS HYDROGEN-BONDING COMPLEXATION IN ZINC-COMPLEXES OF 18-CROWN-6
DOXSEE, KM
HAGADORN, JR
WEAKLEY, TJR
[J]. INORGANIC CHEMISTRY, 1994, 33 (12) : 2600 - 2606
[4] The Cambridge Structural Database
Groom, Colin R.
Bruno, Ian J.
Lightfoot, Matthew P.
Ward, Suzanna C.
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2016, 72 : 171 - 179
[5] CRYSTAL-STRUCTURE ANALYSES OF 1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE AND ITS COMPLEXES WITH LITHIUM PERCHLORATE DIHYDRATE AND LITHIUM THIOCYANATE DIHYDRATE AT - 150-DEGREES-C
GROTH, P
[J]. ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1982, 36 (02): : 109 - 115
[6] A Fivefold Interpenetrating dmd Topological Copper(I) Cyanide Complex Formed by C-C Bond Cleavage of Acetonitrile
Li, Lin
Wang, Chun-Hai
Zhang, Xia-Li
Liu, Xi
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2015, (05) : 859 - 863
[7] Lindoy LF, 1989, CHEM MACROCYCLIC LIG
[8] Three pillared-layered inorganic-organic hybrid polymers with efficient luminescence
Liu, Xi
Zhao, Zhen
Wang, Chun-Hai
Fu, Shan
Huang, Kun-Lin
[J]. RSC ADVANCES, 2017, 7 (64) : 40632 - 40639
[9] Synthesis, crystal structure, and photoluminescence of a dumbbell- like sodium dicyanamide compound with 15-crown-5
Liu, Xi
Ru, Wen-Juan
Zhao, Zhen
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2017, 72 (02): : 167 - 170
[10] Doping potassium ions in silver cyanide complexes for green luminescence
Liu, Xi
Li, Lin
Yang, Yun-Zhi
Huang, Kun-Lin
[J]. DALTON TRANSACTIONS, 2014, 43 (10) : 4086 - 4092

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