1,3-Dipolar cycloaddition of 4-platinumisochromenyliums with an olefin and tandem insertion into benzylic C-H bonds

被引：18

作者：

Kim, Ji Hee ^{[1
]}

Ray, Devalina ^{[1
]}

Hong, Chang Seop ^{[2
]}

Han, Jin Wook ^{[1
]}

Oh, Chang Ho ^{[1
]}

机构：

[1] Hanyang Univ, Dept Chem, Seoul 133791, South Korea

[2] Korea Univ, Dept Chem, Seoul 136704, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 50期

基金：

新加坡国家研究基金会;

关键词：

CONTAINING CARBONYL YLIDES; CATALYZED TANDEM; CYCLIZATION; CONSTRUCTION; GENERATION; ALKENES; ALKYNYL; ETHERS; DERIVATIVES; COMPLEXES;

D O I：

10.1039/c3cc42525h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Isochromenylium-4-ylplatinum(II) species, generated from 1-(2-alkynylphenyl)hex-5-en-1-ones and Pt(II), reacted with a pendant olefin via [3+2] cycloaddition to form tetracyclic Pt-carbene complexes, which underwent C-H insertion with a benzyloxy group at delta or epsilon positions to give highly complex polycycles, which are otherwise hard to access.

引用

页码：5690 / 5692

页数：3

共 50 条

[41] Asymmetric 1,3-dipolar cycloaddition of 4-amino pyrazolone-based azomethine ylides: a straightforward approach to spiropyrazolones
Huang, Yue
Wei, Xingfu
Bao, Xiaoze
Nawaz, Shah
Qu, Jingping
Wang, Baomin
ORGANIC CHEMISTRY FRONTIERS, 2022, 9 (13) : 3585 - 3590
[42] A one-pot synthesis and 1,3-dipolar cycloaddition of [1,2]dithiolo[4,3-b]indole-3(4H)-thiones
Konstantinova, Lidia S.
Lysov, Kirill A.
Amelichev, Stanislav A.
Obruchnikova, Natalia V.
Rakitin, Oleg A.
TETRAHEDRON, 2009, 65 (11) : 2178 - 2183
[43] Versatility of Substituted 1-Formyl-9H-β-carbolines for the Synthesis of New Fused β-Carbolines via Intramolecular 1,3-Dipolar Cycloaddition
Singh, Virender
Hutait, Samiran
Biswas, Subhasish
Batra, Sanjay
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 2010 (03) : 531 - 539
[44] Regioselective preferential C-H activation of sterically hindered 1,3-dienes over [4+2] cycloaddition
Saunthwal, Rakesh K.
Saini, Kapil Mohan
Patel, Monika
Verma, Akhilesh K.
TETRAHEDRON, 2017, 73 (17) : 2415 - 2431
[45] Synthesis of 1,3-Diamines Through Rhodium-Catalyzed C-H Insertion
Kurokawa, Toshiki
Kim, Mihyong
Du Bois, J.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (15) : 2777 - 2779
[46] ONE-POT TANDEM SYNTHESIS OF TETRASUBSTITUTED PYRAZOLES VIA 1,3-DIPOLAR CYCLOADDITION BETWEEN ARYL HYDRAZONES AND ETHYL BUT-2-YNOATE
Ningaiah, Srikantamurthy
Doddaramappa, Shridevi D.
Chandra
Madegowda, Mahendra
Keshavamurthy, Shubakara
Bhadraiah, Umesha K.
SYNTHETIC COMMUNICATIONS, 2014, 44 (15) : 2222 - 2231
[47] Hierarchical Selectivity in Fullerenes: Site-, Regio-, Diastereo-, and Enantiocontrol of the 1,3-Dipolar Cycloaddition to C70
Maroto, Enrique E.
de Cozar, Abel
Filippone, Salvatore
Martin-Domenech, Angel
Suarez, Margarita
Cossio, Fernando P.
Martin, Nazario
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (27) : 6060 - 6064
[48] Asymmetric Inverse-Electron-Demand 1,3-Dipolar Cycloaddition of C,N-Cyclic Azomethine Imines: An Umpolung Strategy
Hashimoto, Takuya
Omote, Masato
Maruoka, Keiji
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (15) : 3489 - 3492
[49] Enantioselective 1,3-Dipolar Cycloaddition of C,N-Cyclic Azomethine Imines to Unsaturated Nitriles Catalyzed by NiII-Pigiphos
Milosevic, Sandra
Togni, Antonio
JOURNAL OF ORGANIC CHEMISTRY, 2013, 78 (19) : 9638 - 9646
[50] Diastereodivergent Synthesis of Chiral 4-Fluoropyrrolidines (exo and exo') Based on the Cu(II)-Catalyzed Asymmetric 1,3-Dipolar Cycloaddition
Kalita, Subarna Jyoti
Cheng, Feng
Fan, Qing-Hua
Shibata, Norio
Huang, Yi-Yong
JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (13) : 8695 - 8705

← 1 2 3 4 5 →