Raman spectroscopy: A promising tool for the characterization of transition metal phosphides

被引：21
作者：
Vereshchagin, Oleg S. [1 ]
Pankin, Dmitrii, V [2 ]
Smirnov, Mikhail B. [3 ]
Vlasenko, Natalia S. [4 ]
Shilovskikh, Vladimir V. [4 ]
Britvin, Sergey N. [1 ,5 ]
机构：
[1] St Petersburg State Univ, Inst Earth Sci, St Petersburg 199034, Russia
[2] St Petersburg State Univ, Ctr Opt & Laser Mat Res, St Petersburg 199034, Russia
[3] St Petersburg State Univ, St Petersburg 199034, Russia
[4] St Petersburg State Univ, Ctr Geoenvironm Res & Modelling Geomodel, St Petersburg 199034, Russia
[5] Russian Acad Sci, Nanomat Res Ctr, Kola Sci Ctr, Apatity 184209, Russia
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2021年 / 853卷
基金：
俄罗斯科学基金会;
关键词：
Iron phosphide; Transition metal; FeP; NiP; Solid solution; Raman spectroscopy; Phonon; Lattice dynamics; HYDROGEN EVOLUTION CATHODE; TETRAHEDRITE-TENNANTITE; IRON PHOSPHIDE; NANOROD ARRAYS; FE-NI; NANOPARTICLES; PERFORMANCE; SCATTERING; EFFICIENT; CRYSTALS;
D O I：
10.1016/j.jallcom.2020.156468
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Transition metal phosphides is a class of compounds which continuously attracts expanding interest in materials science. Raman spectroscopy is one of the basic methods in materials characterization, but it still has rudimentary implications in the analysis of phosphide-based materials. Meanwhile, high spatial resolution and tolerance to the surface quality might place this method in line with the electron microprobe analysis, allowing confident determination of both crystal structure and chemical composition of transition metal phosphides. We herein show the potential applications of Raman spectroscopy for the quantitative analysis of phosphide solid solutions, exemplified by the compounds related to the important join FePeNiP. (C) 2020 Elsevier B.V. All rights reserved.
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页数：8
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