Photocatalytic oxidation of hydrocarbons by a bis-iron(III)-μ-oxo Pacman porphyrin using O2 and visible light

被引：143

作者：

Rosenthal, Joel ^{[1
]}

Luckett, Thomas D. ^{[1
]}

Hodgkiss, Justin M. ^{[1
]}

Nocera, Daniel G. ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 20期

关键词：

D O I：

10.1021/ja058731s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The C-H bonds of hydrocarbons are oxidized catalytically by the electron-deficient Pacman porphyrin, (DPDF)Fe2O, using visible light and molecular oxygen as the terminal oxidant and oxygen atom source. The photocatalytic reactions proceed under mild conditions (ambient temperature and pressure) without the need for an external co-reductant. Copyright © 2006 American Chemical Society.

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页码：6546 / 6547

页数：2

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