Green and Efficient: Oxidation of Aldehydes to Carboxylic Acids and Acid Anhydrides with Air

被引：78

作者：

Liu, Kai-Jian ^{[1
,3
]}

Fu, Yu-Ling ^{[1
]}

Xie, Long-Yong ^{[1
]}

Wu, Chao ^{[1
]}

He, Wei-Bao ^{[1
]}

Peng, Sha ^{[1
]}

Wang, Zheng ^{[1
]}

Bao, Wen-Hu ^{[1
]}

Cao, Zhong ^{[3
]}

Xu, Xinhua ^{[2
]}

He, Wei-Min ^{[1
,2
,3
]}

机构：

[1] Hunan Univ Sci & Engn, Hunan Prov Engn Res Ctr Ginkgo Biloba, Yongzhou 425100, Peoples R China

[2] Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China

[3] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410114, Hunan, Peoples R China

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2018年 / 6卷 / 04期

基金：

中国国家自然科学基金;

关键词：

Oxidation; Aldehyde; Carboxylic acid; Acid anhydride; Air; MOLECULAR-OXYGEN; AEROBIC OXIDATION; CATALYZED OXIDATION; PRIMARY ALCOHOLS; SELECTIVE OXIDATION; BASE-FREE; HYDROGEN-PEROXIDE; WATER; KETONES; ALPHA;

D O I：

10.1021/acssuschemeng.7b04400

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An economic, safe, practical, and environmentally benign protocol for the oxidation of aldehydes to carboxylic acids and acid anhydrides with ambient air as the sole oxidant was developed. This oxidation is operationally simple and external catalyst-, initiator-, and base-free, with outstanding functional group tolerance (moisture-, acid-, base-, and oxidant-sensitive groups). It also provides a practical protocol for large scale synthesis (>100 g), late-stage modification of polyfunctional compounds, and one-pot sequential transformation starting from aldehydes.

引用

页码：4916 / 4921

页数：11

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